{"title":"Cl+和HCl+·与H2反应温度依赖性的再评价","authors":"Paul R. Kemper, Michael T. Bowers","doi":"10.1016/0020-7381(83)85023-2","DOIUrl":null,"url":null,"abstract":"<div><p>The temperature dependence of the reaction of Cl<sup>+</sup> with H<sub>2</sub> has been the subject of several recent studies. The interest in this reaction derives mainly from its importance in modeling chlorine chemistry in interstellar clouds. New data on this reaction are reported that suggest the reaction has a weak negative temperature dependence in agreement with recent flow tube studies. Data for the HD and D<sub>2</sub> isotopic species show the same trend. New data on the HCl<sup>+</sup> + H<sub>2</sub> reaction are also reported.</p></div>","PeriodicalId":13998,"journal":{"name":"International Journal of Mass Spectrometry and Ion Physics","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1983-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-7381(83)85023-2","citationCount":"3","resultStr":"{\"title\":\"Reevaluation of the temperature dependence of the reactions of Cl+ and HCl+· with H2\",\"authors\":\"Paul R. Kemper, Michael T. Bowers\",\"doi\":\"10.1016/0020-7381(83)85023-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The temperature dependence of the reaction of Cl<sup>+</sup> with H<sub>2</sub> has been the subject of several recent studies. The interest in this reaction derives mainly from its importance in modeling chlorine chemistry in interstellar clouds. New data on this reaction are reported that suggest the reaction has a weak negative temperature dependence in agreement with recent flow tube studies. Data for the HD and D<sub>2</sub> isotopic species show the same trend. New data on the HCl<sup>+</sup> + H<sub>2</sub> reaction are also reported.</p></div>\",\"PeriodicalId\":13998,\"journal\":{\"name\":\"International Journal of Mass Spectrometry and Ion Physics\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1983-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0020-7381(83)85023-2\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Mass Spectrometry and Ion Physics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0020738183850232\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Mass Spectrometry and Ion Physics","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020738183850232","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Reevaluation of the temperature dependence of the reactions of Cl+ and HCl+· with H2
The temperature dependence of the reaction of Cl+ with H2 has been the subject of several recent studies. The interest in this reaction derives mainly from its importance in modeling chlorine chemistry in interstellar clouds. New data on this reaction are reported that suggest the reaction has a weak negative temperature dependence in agreement with recent flow tube studies. Data for the HD and D2 isotopic species show the same trend. New data on the HCl+ + H2 reaction are also reported.
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