{"title":"lepidagthis alopecroides甲醇提取物在盐酸中对低碳钢的缓蚀作用","authors":"G. Ndukwe, H. F. Chahul, Godwin Oodo","doi":"10.2478/auoc-2021-0003","DOIUrl":null,"url":null,"abstract":"Abstract We report on the preliminary phytochemical screening of the methanolic extract of the aerial parts of Lepidagathis alopecuroides and its evaluation as a potential corrosion inhibitor for mild steel in aerated 1.0 M HCl by weight loss and linear polarization measurements. Weight loss measurements were conducted at 303, 313, 323 and 333 K. The results showed that L. alopecuroides inhibited the corrosion of mild steel in the acid solution with inhibition efficiency increasing with increase in the concentrations of the plant extract but decreased with increase in temperature. Linear polarization plots showed the plant extract to inhibit both the dissolution of the steel at the anode and the hydrogen evolution reaction (HER) at the cathode making it a mixed inhibitor. Temkin adsorption isotherms best modeled the adsorption of L. alopecuroides extract on the steel surface. From the values of the evaluated kinetic activation parameters in the study, the mechanism of physisorption is proposed for the adsorption of the plant extract on the steel surface.","PeriodicalId":19641,"journal":{"name":"Ovidius University Annals of Chemistry","volume":"1 1","pages":"22 - 27"},"PeriodicalIF":1.0000,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Lepidagathis alopecuroides methanol extract as corrosion inhibitor for mild steel in HCl\",\"authors\":\"G. Ndukwe, H. F. Chahul, Godwin Oodo\",\"doi\":\"10.2478/auoc-2021-0003\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract We report on the preliminary phytochemical screening of the methanolic extract of the aerial parts of Lepidagathis alopecuroides and its evaluation as a potential corrosion inhibitor for mild steel in aerated 1.0 M HCl by weight loss and linear polarization measurements. Weight loss measurements were conducted at 303, 313, 323 and 333 K. The results showed that L. alopecuroides inhibited the corrosion of mild steel in the acid solution with inhibition efficiency increasing with increase in the concentrations of the plant extract but decreased with increase in temperature. Linear polarization plots showed the plant extract to inhibit both the dissolution of the steel at the anode and the hydrogen evolution reaction (HER) at the cathode making it a mixed inhibitor. Temkin adsorption isotherms best modeled the adsorption of L. alopecuroides extract on the steel surface. From the values of the evaluated kinetic activation parameters in the study, the mechanism of physisorption is proposed for the adsorption of the plant extract on the steel surface.\",\"PeriodicalId\":19641,\"journal\":{\"name\":\"Ovidius University Annals of Chemistry\",\"volume\":\"1 1\",\"pages\":\"22 - 27\"},\"PeriodicalIF\":1.0000,\"publicationDate\":\"2021-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Ovidius University Annals of Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2478/auoc-2021-0003\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ovidius University Annals of Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2478/auoc-2021-0003","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 1
摘要
摘要/ Abstract摘要:本文报道了用失重法和线性极化法对Lepidagathis alopecuroides地上部分甲醇提取物在1.0 M HCl中进行初步的植物化学筛选,并对其作为低碳钢缓蚀剂的潜力进行了评价。分别在303、313、323和333 K进行失重测量。结果表明,苦艾草对低碳钢在酸性溶液中的腐蚀有抑制作用,抑制效果随植物提取物浓度的增加而增加,随温度的升高而降低。线性极化图显示,植物提取物既能抑制钢在阳极的溶解,又能抑制阴极的析氢反应(HER),成为一种混合抑制剂。Temkin吸附等温线能很好地模拟钢表面对白花楸提取物的吸附。根据研究中评估的动力学活化参数值,提出了植物提取物在钢表面吸附的物理吸附机理。
Lepidagathis alopecuroides methanol extract as corrosion inhibitor for mild steel in HCl
Abstract We report on the preliminary phytochemical screening of the methanolic extract of the aerial parts of Lepidagathis alopecuroides and its evaluation as a potential corrosion inhibitor for mild steel in aerated 1.0 M HCl by weight loss and linear polarization measurements. Weight loss measurements were conducted at 303, 313, 323 and 333 K. The results showed that L. alopecuroides inhibited the corrosion of mild steel in the acid solution with inhibition efficiency increasing with increase in the concentrations of the plant extract but decreased with increase in temperature. Linear polarization plots showed the plant extract to inhibit both the dissolution of the steel at the anode and the hydrogen evolution reaction (HER) at the cathode making it a mixed inhibitor. Temkin adsorption isotherms best modeled the adsorption of L. alopecuroides extract on the steel surface. From the values of the evaluated kinetic activation parameters in the study, the mechanism of physisorption is proposed for the adsorption of the plant extract on the steel surface.