sba-15负载钴/钌催化剂在促进费托合成中的应用

J. J. Rodrigues, F. Fernandes, M. Rodrigues
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引用次数: 2

摘要

本研究的目的是制备一种以SBA-15为载体的钴/钌催化剂,用于费托合成(FTS)。在513 K, 20 atm, CO:H2摩尔比为1:1的料浆反应器中进行了合成。在SBA-15中加入钴降低了分子筛的比表面积。利用RTP结果找到了氧化铁相的典型温度还原范围。钌的加入提高了费托合成活性和C5+的选择性。活性和选择性的增加归因于活性位点数量的增加,这是由于更高的还原性。
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THE USE OF COBALT/RUTHENIUM CATALYST SUPPORTED IN SBA-15 IN THE PROMOTION OF FISCHER-TROPSCH SYNTHESIS
The aim of this work is to produce a cobalt/ruthenium catalyst supported in SBA-15, for Fischer-Tropsch synthesis (FTS). The synthesis was carried out in a slurry reactor operating at 513 K, 20 atm, and CO:H2 molar ratio of 1:1. The addition of cobalt in SBA-15 decreased the specific superficial area of the molecular sieve. The ranges of temperature reduction typical of iron oxides phases were found using RTP results. Fischer-Tropsch synthesis activity and C5+ hydrocarbon selectivity increased with the addition of Ru. The increase in activity and selectivity were attributed to the increased number of active sites as a result of the higher reducibility.
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