{"title":"理解布格-比尔-朗伯定律的极限","authors":"T. Mayerhöfer, S. Pahlow, Juergen Popp","doi":"10.56530/spectroscopy.iq2368r9","DOIUrl":null,"url":null,"abstract":"The Bouguer-Beer-Lambert law is frequently applied in spectroscopy and spectrophotometry. Often it is assumed that it accurately describes the observed changes induced by light-matter interactions and properly reflects the physical phenomena at play. For most cases, however, this is not true, and issues can arise when the Bouguer-Beer-Lambert law is applied uncritically. In this short article, we will comment on its fundamental limits and their physical background.","PeriodicalId":21957,"journal":{"name":"Spectroscopy","volume":"22 1","pages":""},"PeriodicalIF":0.8000,"publicationDate":"2023-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Understanding the Limits of the Bouguer-Beer-Lambert Law\",\"authors\":\"T. Mayerhöfer, S. Pahlow, Juergen Popp\",\"doi\":\"10.56530/spectroscopy.iq2368r9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The Bouguer-Beer-Lambert law is frequently applied in spectroscopy and spectrophotometry. Often it is assumed that it accurately describes the observed changes induced by light-matter interactions and properly reflects the physical phenomena at play. For most cases, however, this is not true, and issues can arise when the Bouguer-Beer-Lambert law is applied uncritically. In this short article, we will comment on its fundamental limits and their physical background.\",\"PeriodicalId\":21957,\"journal\":{\"name\":\"Spectroscopy\",\"volume\":\"22 1\",\"pages\":\"\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2023-08-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Spectroscopy\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.56530/spectroscopy.iq2368r9\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"SPECTROSCOPY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectroscopy","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.56530/spectroscopy.iq2368r9","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"SPECTROSCOPY","Score":null,"Total":0}
Understanding the Limits of the Bouguer-Beer-Lambert Law
The Bouguer-Beer-Lambert law is frequently applied in spectroscopy and spectrophotometry. Often it is assumed that it accurately describes the observed changes induced by light-matter interactions and properly reflects the physical phenomena at play. For most cases, however, this is not true, and issues can arise when the Bouguer-Beer-Lambert law is applied uncritically. In this short article, we will comment on its fundamental limits and their physical background.
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