组成对铜(II)-氢氧化钴(II)硝酸盐固溶体晶格参数和热行为的影响

K. Petrov, N. Zotov, O. García-Martínez, P. Millán, R.M. Rojas
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引用次数: 4

摘要

铜(II)-钴(II)氢氧化物硝酸盐固溶体的热分解,CuxCo2−x(OH)3NO3 (0 <用热学和x射线衍射技术研究了空气中x < 2.0)。结果表明,形成的固溶体为部分有序的取代型,热分解过程中的反应顺序取决于化学计量系数x的值。
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Effect of the composition on the lattice parameters and thermal behaviour of copper(II)-cobalt(II) hydroxide nitrate solid solutions

The thermal decomposition of copper(II)-cobalt(II) hydroxide nitrate solid solutions, CuxCo2−x(OH)3NO3 (0 < x ⩽ 2.0) in air has been studied by thermal and X-ray diffraction techniques. It has been shown that the solid solutions formed are of a partially-ordered, substitutional type and that the reaction sequence during the thermal decomposition depends on the value of the stoichiometric coefficient x.

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