K. Petrov, N. Zotov, O. García-Martínez, P. Millán, R.M. Rojas
{"title":"组成对铜(II)-氢氧化钴(II)硝酸盐固溶体晶格参数和热行为的影响","authors":"K. Petrov, N. Zotov, O. García-Martínez, P. Millán, R.M. Rojas","doi":"10.1016/0168-7336(89)80056-7","DOIUrl":null,"url":null,"abstract":"<div><p>The thermal decomposition of copper(II)-cobalt(II) hydroxide nitrate solid solutions, Cu<sub><em>x</em></sub>Co<sub>2−<em>x</em></sub>(OH)<sub>3</sub>NO<sub>3</sub> (0 < <em>x</em> ⩽ 2.0) in air has been studied by thermal and X-ray diffraction techniques. It has been shown that the solid solutions formed are of a partially-ordered, substitutional type and that the reaction sequence during the thermal decomposition depends on the value of the stoichiometric coefficient <em>x</em>.</p></div>","PeriodicalId":101061,"journal":{"name":"Reactivity of Solids","volume":"7 4","pages":"Pages 359-369"},"PeriodicalIF":0.0000,"publicationDate":"1989-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0168-7336(89)80056-7","citationCount":"4","resultStr":"{\"title\":\"Effect of the composition on the lattice parameters and thermal behaviour of copper(II)-cobalt(II) hydroxide nitrate solid solutions\",\"authors\":\"K. Petrov, N. Zotov, O. García-Martínez, P. Millán, R.M. Rojas\",\"doi\":\"10.1016/0168-7336(89)80056-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The thermal decomposition of copper(II)-cobalt(II) hydroxide nitrate solid solutions, Cu<sub><em>x</em></sub>Co<sub>2−<em>x</em></sub>(OH)<sub>3</sub>NO<sub>3</sub> (0 < <em>x</em> ⩽ 2.0) in air has been studied by thermal and X-ray diffraction techniques. It has been shown that the solid solutions formed are of a partially-ordered, substitutional type and that the reaction sequence during the thermal decomposition depends on the value of the stoichiometric coefficient <em>x</em>.</p></div>\",\"PeriodicalId\":101061,\"journal\":{\"name\":\"Reactivity of Solids\",\"volume\":\"7 4\",\"pages\":\"Pages 359-369\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1989-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0168-7336(89)80056-7\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Reactivity of Solids\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0168733689800567\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Reactivity of Solids","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0168733689800567","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Effect of the composition on the lattice parameters and thermal behaviour of copper(II)-cobalt(II) hydroxide nitrate solid solutions
The thermal decomposition of copper(II)-cobalt(II) hydroxide nitrate solid solutions, CuxCo2−x(OH)3NO3 (0 < x ⩽ 2.0) in air has been studied by thermal and X-ray diffraction techniques. It has been shown that the solid solutions formed are of a partially-ordered, substitutional type and that the reaction sequence during the thermal decomposition depends on the value of the stoichiometric coefficient x.