丙烯酸-g-(-卡拉胶)共聚物的合成、表征及应用研究

A. Srivastava, R. Kumar
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引用次数: 17

摘要

研究了过氧单硫酸盐浓度、巯基琥珀酸浓度、氢离子浓度、丙烯酸浓度和卡拉胶浓度对接枝参数的影响,找出了最大接枝率。相应的值分别为、、、mol dm−3和g dm−3。最佳反应时间为120 min,反应温度为40℃。从5.0到mol dm−3的氢离子变化对接枝参数的影响迅速变化。发现接枝共聚物比未接枝的基底更热稳定。接枝共聚物也吸收了更多的水,即有害的金属阳离子。Hg2
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Synthesis and Characterization of Acrylic Acid-g-(-Carrageenan) Copolymer and Study of Its Application
The effects of concentrations of peroxymonosulphate, mercaptosuccinic acid, hydrogen ion, acrylic acid, and carrageenan on grafting parameters were studied to find out the maximum grafting ratio. The corresponding values were found to be , , ,  mol dm−3, and  g dm−3, respectively. The optimal reaction time duration and reaction temperature were found to be 120 min and 40°C, respectively. The effect of hydrogen ion variation from 5.0 up to  mol dm−3 shows prompt changes on grafting parameter. The grafted copolymer was found more thermally stable than the ungrafted substrate. Also the grafted copolymer absorbed more water, namely hazardous metal cations. Hg2
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