导电有机聚合物基无机-有机杂化复合材料的合成与表征

IF 0.1 Q4 POLYMER SCIENCE Journal of Polymer & Composites Pub Date : 2020-04-08 DOI:10.37591/jopc.v8i1.3769
A. Devi, H. Sharma, Mukesh Kumar
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引用次数: 0

摘要

无机有机(IO)杂化材料是解决现代技术官僚社会许多技术问题的最有前途的候选者之一,其中插入导电有机聚合物(COP)在杂化材料上刻印其聚合物性质。采用“即热慢冷”技术合成了对甲苯胺(有机)与氯化汞(无机)的无机-有机杂化材料。得到了一些浅橙色的片状晶体。对生长晶体的XRD谱图进行了分析,结果表明该晶体生长为a≠b≠c [10.061(4) a≠4.317(2)a≠12.987(5)a], α=γ= 90 o≠β [α =γ= 90 o, β=104.322(7) o]的单斜晶系,属于空间群p2 1,二次相互作用分析表明该材料在光电子领域具有潜在的应用前景。
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Conductive Organic Polymer Based Inorganic-Organic Hybrid Composite: Synthesis and Characterization
Inorganic organic (IO) hybrids where inserted conducting organic polymer (COP) imprints their polymeric nature onto the hybrid material are one of the most promising candidates for solving many technological problems of modern technocratic society. The Inorganic-organic hybrid material of para toluidine (organic) & mercuric chloride (inorganic) was synthesized by using “instant-heating and slow-cooling” technique. Some light orange coloured plate-like crystals were obtained. XRD pattern of the grown crystal were analysed which shows that crystal has been grown into monoclinic crystal system in which a ≠ b ≠ c [10.061(4) A ≠ 4.317(2) A ≠ 12.987(5) A] & α=γ= 90 o ≠ β [α = γ = 90 o , β=104.322(7) o ] and belongs to space group p2 1 .Analysis of secondary interactions shows that such material has potential application in opto electronics.
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