纳米硅-腐殖质的制备及其初步评价

Yu. D. Smirnova, G. Rabinovich, N. Fomicheva
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摘要

摘要:近几十年来,纳米技术的发展和应用取得了重大进展,包括在农业的各个领域。人们一直在积极寻找利用纳米颗粒制备植物生长制剂的方法,以更快地参与植物的代谢过程。本文旨在获得一种纳米二氧化硅-腐殖质制剂及其在马铃薯上的应用。作为腐植酸物质的来源,液体腐植酸制剂BoGum(由全俄开垦土地研究所开发)被用作硅-硅酸钠的来源。采用超声分散法实现了样品的纳米级。在BoGum中加入0.1% (SiO2)的硅源,然后应用超声波作用5、10、15和20分钟。使用90 Plus/MAS粒度分析仪对所得样品进行分析表明,随着分散时间的增加,有效粒径变化不显著。同时,颗粒的重新分布也被注意到:当样品暴露20分钟时,小颗粒的数量增加了。处理5分钟后,颗粒分布范围为115±13-830±23 nm,处理20分钟后,颗粒直径下降到81±8-120±10 nm和280±4-470±18 nm两个区域。超声波作用有助于所获得的制剂保持稳定的聚集状态,与不使用超声波的硅-腐植酸制剂相比,获得了更大的微生物活性和更大的腐植酸含量。新型纳米二氧化硅-腐殖质制剂已在马铃薯上进行了试验。种植前对块茎进行处理,然后对营养植物进行叶面喷施,马铃薯产量提高了18.7%。土壤中单硅酸和聚硅酸含量的变化,以及马铃薯顶部硅的积累,当施用硅腐殖剂时,平均为绝对干质量的0.96%。
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Obtaining a nanosized silica-humic preparation and its initial approbation
Abstract: The recent decades have witnessed a significant development and implementation of nanotechnology, including in various branches of agriculture. There is an active search for ways to obtain preparations for plant growing with nanoparticles that can be more rapidly involved in the metabolic processes of plants. This article aims to obtain a nanosized silica-humic preparation and its approbation on potato plants. As a source of humic substances, a liquid humic preparation BoGum (developed by the All-Russian Research Institute of Reclaimed Lands) was used, as a source of silicon – sodium metasilicate. Ultrasonic dispersion method was used for achieving the nanoscale of the samples. A silicon source was introduced in an amount of 0.1% (of SiO2) into BoGum, followed by the application of ultrasonic action for 5, 10, 15 and 20 minutes. The analysis of the obtained samples using a 90 Plus/MAS particle size analyzer has shown that with increasing dispersion time, the effective particle diameter changed insignificantly. At the same time, a redistribution of particles was noted: when the samples were exposed for 20 minutes, the number of smaller particles increased. After 5 minutes of treatment, the range of particle distribution was 115±13–830±23 nm, after 20 minutes of exposure, the particle diameter fell into two regions: 81±8–120±10 and 280±4–470±18 nm. Ultrasonic action contributed to the retention of the stable state of aggregation of the obtained preparation, larger microbiological activity and larger content of humic acid in comparison with the silica-humic preparation, obtained without the application of an ultrasound. The new nanosized silica-humic preparation has been tested on potato plants. Treatment of tubers before planting, followed by foliar spraying of vegetative plants, has contributed to an increase in potato yield by 18.7%. Changes were noted in the content of mono- and polysilicic acids in the soil, as well as the accumulation of silicon in the tops of potatoes when using silicahumic preparations by 0.96% of absolute dry mass on average.
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