{"title":"铁(III)介导的环丙酮缩醛的氧化环化","authors":"K. Booker‐Milburn, B. Cox, T. Mansley","doi":"10.1039/CC9960002577","DOIUrl":null,"url":null,"abstract":"Treatment of the cyclopropanone acetals 7 or 11 with three different FeIII species gives the lactone 9 and the ester 13 respectively via an oxidative cyclopropane cleavage followed by a 5-exo radical cyclisation–abstraction sequence.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":"73 1","pages":"2577-2578"},"PeriodicalIF":0.0000,"publicationDate":"1996-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"5","resultStr":"{\"title\":\"Iron (III) Mediated Oxidative Cyclisations of Cyclopropanone Acetals\",\"authors\":\"K. Booker‐Milburn, B. Cox, T. Mansley\",\"doi\":\"10.1039/CC9960002577\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Treatment of the cyclopropanone acetals 7 or 11 with three different FeIII species gives the lactone 9 and the ester 13 respectively via an oxidative cyclopropane cleavage followed by a 5-exo radical cyclisation–abstraction sequence.\",\"PeriodicalId\":17282,\"journal\":{\"name\":\"Journal of The Chemical Society, Chemical Communications\",\"volume\":\"73 1\",\"pages\":\"2577-2578\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1996-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"5\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society, Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/CC9960002577\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/CC9960002577","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Iron (III) Mediated Oxidative Cyclisations of Cyclopropanone Acetals
Treatment of the cyclopropanone acetals 7 or 11 with three different FeIII species gives the lactone 9 and the ester 13 respectively via an oxidative cyclopropane cleavage followed by a 5-exo radical cyclisation–abstraction sequence.
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