{"title":"5,15-二苯基卟啉的碘化和Heck炔基化。不对称中位取代卟啉的方便入口","authors":"R. Boyle, Claire K. Johnson, D. Dolphin","doi":"10.1039/C39950000527","DOIUrl":null,"url":null,"abstract":"Iodination of 5,15-diphenylporphyrin followed by metallation and palladium(0) catalysed coupling with monosubstituted acetylenes gives zinc(II)-10-(2-substituted-alkynyl)-5,15-diphenylporphyrins.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1995-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"58","resultStr":"{\"title\":\"Iodination and Heck alkynylation of 5,15-diphenylporphyrin. A convenient entry to asymmetrically meso-substituted porphyrins\",\"authors\":\"R. Boyle, Claire K. Johnson, D. Dolphin\",\"doi\":\"10.1039/C39950000527\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Iodination of 5,15-diphenylporphyrin followed by metallation and palladium(0) catalysed coupling with monosubstituted acetylenes gives zinc(II)-10-(2-substituted-alkynyl)-5,15-diphenylporphyrins.\",\"PeriodicalId\":17282,\"journal\":{\"name\":\"Journal of The Chemical Society, Chemical Communications\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1995-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"58\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society, Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C39950000527\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950000527","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Iodination and Heck alkynylation of 5,15-diphenylporphyrin. A convenient entry to asymmetrically meso-substituted porphyrins
Iodination of 5,15-diphenylporphyrin followed by metallation and palladium(0) catalysed coupling with monosubstituted acetylenes gives zinc(II)-10-(2-substituted-alkynyl)-5,15-diphenylporphyrins.
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