氟醚。沟通3。在环氧化物中加入醇制备氟化醚、氟烯烃和醇与甲醛的相互作用、酯交换、电化学氟化和许多其他方法。

V. Kornilov
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引用次数: 0

摘要

本文最后介绍了几种制备氟醚的方法:环氧化物加成醇法、氟化烯烃和氟化醇与甲醛的相互作用法、醚化法和电化学氟化法。此外,还简要介绍了未包括在单独各章中的氟化醚的获取方法,即:含氟烯烃与醚的自由基加成、变价金属与单质氟和高氟化物的氟化、醇与酮和羧酸的反应、全氟亚硝基烷烃与醇的反应以及醇与2,4,6-三-(2,2,2-三氟乙氧基)-[1,3,5]三嗪(TriTFET)的相互作用。
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Fluorinated ethers. Communication 3. Preparation of fluorinated ethers by addition of alcohols to epoxides, interaction of fluoroolefins and alcohols with formaldehyde, transesterification, electrochemical fluorination and a number of other methods.
The following methods of obtaining fluorinated ethers are described in the final part of the review: the addition of alcohols to epoxides, the interaction of fluorinated olefins and alcohols with formaldehyde, transetherification, and electrochemical fluorination. In addition, a brief description of methods for obtaining fluorinated ethers that are not included in the separate chapters is given, namely: free radical addition of fluorine-containing alkenes to ethers, fluorination with elemental fluorine and higher fluorides of metals of variable valence, reactions of alcohols with ketones and carboxylic acids, reactions of perfluorinated nitrosoalkanes with alcohols and interaction of alcohols with 2,4,6-tris-(2,2,2-trifluoroethoxy)-[1,3,5]triazine (TriTFET).
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