改性聚氯乙烯化学结构的新方法

Amer A.Hasan, Mohammed H. Al-mashhadani, Wedad H. Al-Dahhan, Rahimi M.Yusop, Emad A. Yousif
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摘要

自19世纪首次发现聚氯乙烯以来,聚合物研究人员一直在继续研究聚氯乙烯。它的特性,如热不稳定性,由于其含有氯原子作为良好的离去基对紫外线敏感而产生的结构缺陷而变得微妙。许多研究者建议添加各种有机和无机添加剂作为聚氯乙烯的光稳定剂和/或热稳定剂。最近,这项工作得到了广泛的扩展,正在进行的研究是通过用其他分子取代部分氯原子来改变聚氯乙烯的化学结构,从而提高其抗风化环境的稳定性。最后一种方法不仅适用于常见的化学反应,而且也适用于改善聚氯乙烯在特定应用中的性能。根据过去十年的报告,本研究概述了聚氯乙烯的许多化学变化及其相关用途。这些变化是通过碳-碳和碳-氮键对聚氯乙烯进行改性后组织起来的。
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Recent Approaches to Modify Poly(vinyl chloride) Chemical Structure
Since its first discovery in the nineteenth century, polymer researchers have continued to study poly(vinyl chloride). Its characteristics, such as its thermal instability, are delicate by its structural flaws that result from its containing chlorine atom which is sensitive to UV light as a good leaving group. Many researchers suggested adding various types of organic and inorganic additives as photo and/or thermal stabilizers of poly(vinyl chloride). Recently this work has been expanded by extensive ongoing research to modify the chemical structure of poly(vinyl chloride) by replacing part of the chlorine atoms with other molecules which could enhance its stability against weathering circumstances. The last was carried out not only for common chemical reactions but also to improve the characteristics of poly(vinyl chloride) in particular applications. Basedon reports from the past ten years, this study outlines many of the chemical alterations of poly(vinyl chloride) as well as associated uses. These alterations are organized following the modification of poly(vinyl chloride) through Carbon-Carbon and Carbon-Nitrogen linkages.
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