蒙古部分煤的表征及热解研究

P. Barnasan, Batkhishig Damdin, B. Sanjaa, Battsetseg Munkhtaivan, Ankhtuya Ariunbold, Jargalmaa Soninkhuu, Avid Budeebazar, A. Aleksandr, P. Kuznetsov
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摘要

本文报道了蒙古Tavan tolgoi、narin sukhait、Baganuur和Shivee-Ovoo 4个矿床煤的技术特征、煤的有机元素组成和煤灰的无机元素组成。采用热重分析方法对煤样中有机质进行了热稳定性分析,并详细探讨了煤样有机质的热分解机理。在不同加热温度下对煤样进行热解处理,测定热解产物如硬渣、冷凝液(焦油和热解水)和未冷凝气产物的产率。对所选煤的煤灰进行了详细的研究,并报道了塔班陶勒盖和纳林苏哈伊特矿床的高阶煤灰分具有酸性,巴格努尔和Shivee-Ovoo矿床的低阶煤灰分具有碱性。此外,对Tavan tolgoi、Nariin sukhait、Shivee-Ovoo和Baganuur矿床的煤样进行了不同加热温度下的热解处理,并测定了热解产物如硬渣、冷凝液(焦油和热解水)和非冷凝气产物的产率。塔班陶勒盖和纳林苏哈伊特高阶煤的硬渣产率高于巴格努尔煤和Shivee-Ovoo煤的低阶煤。对热解后的脱水焦油进行了化学成分分析。
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Investigation on Characterization and Pyrolysis of Some Coals from Mongolia
This study reports the technical characteristics, the organic elemental composition of coal, and the inorganic elemental composition of coal ashes from four selected coals including Tavan tolgoi, Nariin sukhait, Baganuur and Shivee-Ovoo deposits in Mongolia. The thermal stability analyses of the organic mass in coal samples were also conducted with thermogravimetric analysis and discussed with the detailed mechanisms of the thermal decomposition of the coal organic mass. Furthermore, the coal samples were processed by pyrolysis at different heating temperatures and determined the yields of pyrolysis products such as hard residue, condensed liquid (tar and pyrolysis water), and uncondensed gas products. The coal ashes from the selected coals were also studied in detail and report that the ashes of high-rank coals of Tavan tolgoi and Nariin sukhait deposits have acidic character and ashes of low-rank coals of Baganuur and Shivee-Ovoo deposits have alkaline character. In addition, the coals samples from Tavan tolgoi, Nariin sukhait, Shivee-Ovoo, and Baganuur deposits were processed by pyrolysis at different heating temperatures and determined with the yields of pyrolysis products such as hard residue, condensed liquid (tar and pyrolysis water), and uncondensed gas products. The yields of hard residue from high-rank coals of Tavan tolgoi and Nariin sukhait were higher than that of low-rank coals of Baganuur and Shivee-Ovoo coal. The dewatered tar products of pyrolysis were investigated for chemical composition analysis.
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