电荷和极化现象中柯氏弛豫的机制

K. Ngai, A. Rajagopal, R. Rendell, S. Teitler
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引用次数: 0

摘要

本文简要地引用了R.和F. Kohlrausch对复杂系统中机械弛豫和介电弛豫的贡献,作为讨论弛豫理论的背景,该理论推导出Kohlrausch随时间变化的弛豫率,该弛豫率可以表示为W0(ωct)−n, 0p)1−n]弛豫函数。这里W0是一些定义明确的原始弛豫种的基本弛豫速率。得到了两个耦合预测。它们已经过实验验证,并已成功应用于与驻极体相关的电导率和极化现象,以及粘弹性、流变学等。
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Mechanisms for Kohlrausch relaxations in charging and polarization phenomena
The contributions of R. and F. Kohlrausch to the description of mechanical and dielectric relaxation in complex systems are briefly cited as background for a discussion of a theory of relaxation that derives both the Kohlrausch time-dependent relaxation rate that can be expressed in the form W0ct)−n, 0p)1−n] relaxation function. Here W0 is the fundamental relaxation rate of some well-defined primitive relaxation species. Two coupled predictions are obtained. They have been experimentally verified and have led to many successful applications to conductivity and polarization phenomena relevant to electrets, as well as viscoelasticity, rheology, etc.
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