M. Ryan, I. Abu-Yousef, A. Rys, C. Cheer, D. Harpp
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引用次数: 3
摘要
建立了三硫化二烯基硒5的x射线晶体结构测定方法。C 38 H 30 S 2 Se, Mr=629.74，单斜，p 21 / n, a =14.078(4)， b =12.852(4)， C =17.171(6) Å， β=98.08(2)°。V =3070.7 Å 3, Z =4, Do=1.37 g/cm 3, MoK α， λ=0.71069 Å， μ=14.66 cm−1,F (000)=370, T =293(2) K, R (R w)=0.0355(0.0342)，对2895个观测到的独立反射[F >2.5σ(F)]，拟合优度=1.104。该材料由三烷基硫醇6与第一种硒转移试剂双- N -苯并三唑-1-基硒化物7反应而得。
The X-ray crystal structure determination of ditritylseleno trisulfide 5 was obtained. C 38 H 30 S 2 Se, Mr=629.74, monoclinic, p 2 1 / n , a =14.078(4), b =12.852(4), c =17.171(6) Å, β=98.08(2)°. V =3070.7 Å 3 , Z =4, Do=1.37 g/cm 3 , MoK α , λ=0.71069 Å, μ=14.66 cm −1 , F (000)=370, T =293(2) K, R ( R w )=0.0355(0.0342) for 2895 observed independent reflections [ F >2.5σ( F )], goodness of fit=1.104. The material was obtained by reacting trityl thiol 6 with the first selenium transfer reagent bis- N -benzotriazol-1-yl selenide 7 .
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