环己环[5.3.1]推进剂作为紫杉醇ABC环体系的前体

M. Banwell, R. Gable, S. Peters, J. R. Phyland
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引用次数: 11

摘要

环己环[5.3.1]推进剂如7和8的热或银离子诱导的电环开环提供了紫杉醇(紫杉醇)的ABC环类似物,包括化合物10、11和14。
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Cyclohexannulated [5.3.1]propellanes as precursors to the ABC ring system of paclitaxel (taxolTM)
Thermal or silver-ion induced electrocyclic ring-opening of Cyclohexannulated [5.3.1]propellanes such as 7 and 8 provides ABC ring analogues of paclitaxel (taxol) including compounds 10, 11 and 14.
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