“银-聚对苯二甲酸乙二醇酯”复合材料的力学性能和结构研究

D. Panov
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引用次数: 0

摘要

采用基体合成法制备了“银-聚合物”复合材料样品。采用不同孔径和不同浓度的聚对苯二甲酸乙二醇酯制成的轨道膜作为基质。通过电化学沉积填充基体孔隙。本文研究了该复合材料的结构和力学性能,该复合材料是一种多孔聚合物基质,其纳米和微丝银沉积在孔隙中。通过拉伸实验确定了试样的力学性能。利用扫描电子显微镜的方法,发现在同一样品中填充PET基体孔隙的纳米线和微线的长度不相同,而观察到纳米线和微线频繁的相互交叉,并通过SEM显微图像确定了纳米线和微线的浓度。利用先前开发的基于单键法的技术计算了纳米线和微线的交叉概率和交叉数。结果表明,金属-聚合物复合材料的力学性能受导线相交次数和相同浓度下导线直径的显著影响。
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Study of the mechanical properties and structure of the “silver – polyethylene terephthalate” composite
Samples of the “silver – polymer” composite were obtained by the matrix synthesis method. Track membranes made of polyethylene terephthalate with pores of different diameters and with different concentrations were used as a matrix. The matrix pores were filled by electrochemical deposition. The structure and mechanical properties of this composite, which is a porous polymer matrix with nano- and microwires of silver deposited into pores, have been studied. Mechanical properties were determined experimentally by stretching the samples. Using the method of scanning electron microscopy, it was found that the length of nano- and microwires filling the pores of the PET matrix is not the same in the same sample, while frequent mutual intersection of the wires was observed, the concentrations of nano- and microwires were determined from SEM microimages. The crossing probability and the number of crossing nano- and microwires were calculated using a previously developed technique based on the single bond method. It is shown that the mechanical properties of the metal-polymer composite are significantly affected by the number of wire intersections and, at the same concentration of wires, their diameter.
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