{"title":"苯胺中n -芳基键的旋转受阻","authors":"M. Filleux-Blanchard, J. Fieux, J. Halle","doi":"10.1039/C29710000851","DOIUrl":null,"url":null,"abstract":"There is a correlation between activation parameters and the steric and electronic effects of the ring substituents in hindered rotation about the N–aryl bond in N-unsubstituted anilines.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"7 1","pages":"851-852"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Hindered rotation about the N–aryl bond in anilines\",\"authors\":\"M. Filleux-Blanchard, J. Fieux, J. Halle\",\"doi\":\"10.1039/C29710000851\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"There is a correlation between activation parameters and the steric and electronic effects of the ring substituents in hindered rotation about the N–aryl bond in N-unsubstituted anilines.\",\"PeriodicalId\":17278,\"journal\":{\"name\":\"Journal of The Chemical Society D: Chemical Communications\",\"volume\":\"7 1\",\"pages\":\"851-852\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society D: Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C29710000851\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society D: Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C29710000851","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Hindered rotation about the N–aryl bond in anilines
There is a correlation between activation parameters and the steric and electronic effects of the ring substituents in hindered rotation about the N–aryl bond in N-unsubstituted anilines.