二吡啶配位超分子多孔聚合物六水四苯-1,2,4,5-碳酸四铁(iii)加合物的合成及结构化学研究

B. T. Usubaliyev, D. Taghiyev, M. Munshiyeva, G. M. Aliyeva, Aliyeva Fb, A. Rzayeva, Hasanova Mm, P. Safarova, G. Mammadova
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引用次数: 0

摘要

首次合成了具有多孔结构的配合物六碳四苯-1,2,4,5-四碳四铁(III)的α, α ' -二吡啶加合物。根据元素分析、x射线分析、红外光谱分析和差热分析结果,确定了酸阴离子与二吡啶的个性、化学式、热破坏和配位形式。配合物与二吡啶相互作用时,完全失去水的结晶分子,生成化学式为Fe4(C6H2(COO)4)3(dpy)2(二吡啶)的化合物。通过衍射图的识别,确定了配合物的晶格单元参数。
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Synthesis and Structural-chemical Studied of Adduct of Coordination Supramolecular Porous Polymer Hexaaquatribenzene-1,2,4,5- Teacarbonato-tetrairon(iii) with Dipyridyl
An α, α′-dipyridyl adduct of a complex compound hexaaquatribenzene-1,2,4,5-tetracarbonatotetra iron (III) with porous structure was synthesized for the first time. According to the results of elemental, X-ray, IR-spectroscopic and differential-thermal analyses the individuality, chemical formula, thermal destruction, and form of coordination of acid-ic anion and dipyridyl were established. During interaction of a complex compound with dipyridyl, it completely loses all crystallization molecule of water resulting in a compound with a chemical formula of Fe4(C6H2(COO)4)3(dpy)2 (dipyridyl). Using the identification of diffraction pattern the parameters of lattice cell of the complex compound were determined.
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