紫外光对含芳香胺聚氯乙烯片材的影响

S. M. Abdullah, Aseel F.Alwan, Atheer M. Majeed
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摘要

采用聚氯乙烯与芳香胺、二甲基氨基苯甲醛(No.1)、氨基苯酚(No.2)、联苯胺(No.3)和4,4-二氨基二苯基砜(No.4)在340nm紫外光源下进行了研究。监测了羰基和多烯基团的FTIR光谱变化,计算了不同辐照时间下的I(C=C)和I(C= o),并采用粘度法计算了PVC和PVC采用片材的分子量。结果表明,芳香胺类光稳定剂的稳定性依次为:No.1≈No.2≈No.3>No.4。通过AFM分析获得板材表面形貌,得到辐照前毛坯、2号、4号板材的粗糙度系数(Rq)分别为(Rq=73.0)、(Rq=240)、(Rq=213),辐照后的粗糙度系数(Rq=180)、(Rq=281)、(Rq=285)。
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The Influence of the UV Light on the PVC Sheets Adopted with Some Aromatic Amines
Adopted PVC with aromatic amines,(dimethyl amino benzyldehyde(No.1), aminophenol(No.2),benzidine (No.3)and 4,4-diaminodiphenylsulphone(No.4) were investigated using UV light source at 340nm. the changing in FTIR spectroscopy for carbonyl and polyene groups was monitored, I(C=C)and I(c=o)was calculated during different period of irradiation time, in addition, the molecular weight of PVC and PVC adopted sheets was obtained using viscosity method. the results show the aromatic amines behave as a good photostabilizer in order: No.1≈No.2≈No.3>No.4. The morphology of the sheets surface achieved by AFM analysis which assigned that the roughness factor (Rq) of the blank, No.2 and No.4 sheets was (Rq=73.0), (Rq=240), (Rq=213) before irradiation and (Rq=180), (Rq=281), (Rq=285) after radiation respectively.
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