{"title":"伯烷基自由基在双甲磺酰肟醚分子间加成的近似速率常数","authors":"Sunggak Kim, Yukwan Song","doi":"10.1016/S1387-1609(01)01258-0","DOIUrl":null,"url":null,"abstract":"<div><p>An approximate rate constant for the intermolecular addition of a primary alkyl radical onto bis-methanesulfonyl oxime ether <strong>2</strong> has been measured to be <em>k</em><sub>a</sub> = 1.7·10<sup>6</sup> M<sup>–1</sup>·s<sup>–1</sup> at 80 <sup>o</sup>C, which is in reasonably good agreement with the data obtained from competition experiments.</p></div>","PeriodicalId":100305,"journal":{"name":"Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry","volume":"4 6","pages":"Pages 431-433"},"PeriodicalIF":0.0000,"publicationDate":"2001-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1387-1609(01)01258-0","citationCount":"0","resultStr":"{\"title\":\"Approximate rate constant for the intermolecular addition of a primary alkyl radical onto bis-methanesulfonyl oxime ether\",\"authors\":\"Sunggak Kim, Yukwan Song\",\"doi\":\"10.1016/S1387-1609(01)01258-0\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>An approximate rate constant for the intermolecular addition of a primary alkyl radical onto bis-methanesulfonyl oxime ether <strong>2</strong> has been measured to be <em>k</em><sub>a</sub> = 1.7·10<sup>6</sup> M<sup>–1</sup>·s<sup>–1</sup> at 80 <sup>o</sup>C, which is in reasonably good agreement with the data obtained from competition experiments.</p></div>\",\"PeriodicalId\":100305,\"journal\":{\"name\":\"Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry\",\"volume\":\"4 6\",\"pages\":\"Pages 431-433\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2001-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S1387-1609(01)01258-0\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1387160901012580\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1387160901012580","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Approximate rate constant for the intermolecular addition of a primary alkyl radical onto bis-methanesulfonyl oxime ether
An approximate rate constant for the intermolecular addition of a primary alkyl radical onto bis-methanesulfonyl oxime ether 2 has been measured to be ka = 1.7·106 M–1·s–1 at 80 oC, which is in reasonably good agreement with the data obtained from competition experiments.
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