纳米二氧化硅表面处理对矿物油击穿强度的影响

Huifei Jin, P. Morshuis, J. Smit, T. Andritsch
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引用次数: 26

摘要

在之前的工作中,交流击穿测试的结果表明,未经改性的二氧化硅纳米颗粒提高了矿物油基纳米流体的击穿强度,特别是在相对较高的湿度水平(约25 ppm)下。我们提出,由于未经改性的二氧化硅纳米颗粒的亲水表面可以吸收水分,这将导致油中大块的自由水分减少,这对击穿强度有很大的影响。在本研究中,通过比较两种矿物油基纳米流体的击穿强度来验证这一观点:一种是未经改性的二氧化硅纳米流体,另一种是经过Z-6011改性的二氧化硅纳米流体。硅烷偶联剂Z-6011使二氧化硅纳米颗粒表面疏水,从而防止水吸附。
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The effect of surface treatment of silica nanoparticles on the breakdown strength of mineral oil
In previous work, the results of AC breakdown tests showed that unmodified silica nanoparticles improve the breakdown strength of mineral oil based nanofluids, especially at a relatively high humidity level of around 25 ppm. It was proposed that, since the hydrophilic surface of unmodified silica nanoparticles can absorb water, this would lead to a reduction of free moisture in the bulk of the oil, which has a strong influence on the breakdown strength. In the present study this proposition is verified, by comparing the breakdown strength of two mineral oil based nanofluids: a reference with unmodified silica nanofluid and a nanofluid with Z-6011 modified silica. The silane coupling agent Z-6011 turns the surface of silica nanoparticles hydrophobic, thus preventing water adsorption.
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