{"title":"含铂玻璃多晶材料的机械强度","authors":"M. Tashiro, S. Sakka, M. Wada","doi":"10.2109/JCERSJ1950.68.778_223","DOIUrl":null,"url":null,"abstract":"S tive in preventing formation of either of those structural imperfections associated with trapped electrons or positive holes holes. As to the valency changes of cerium ion itself, a small part of trivalent cerium ions was found to loose their electron upon irradiation by the reaction Ce\" hu—> [Ce\" with positive hole] + e-. Use of Ordinary Plate Glass as a Gamma-Ray Dosimeter Megumi TASHIRO, SUMi0 SAKKA and Naohiro SOGA Yogyo Kyokaishi (Jo urnal of the Ceramic Association, Japan), 68, 191 (1960) The gamma-ray dose rate distribution in a small closed space, 80mm in dia., 110mm in height, was determined by the use of small pieces of ordinary plate glass, 15 x 6 x 1.72mm, as a dosimeter. The technique of the measurement was described. The advantageous features of the glass dosimeter, i. e., its small size, convenient usage, and preciseness in the measurement, were discussed. A brief description of the construction of a small Co-60 irradiator, in which the measurement was made, was appended. Mechanicel Strength of Polycrystalline Materials Propuced from Platinum Containing Glasses Megumi TASHIRO, Sumio SAKKA and Masamichi WADA Yogyo Kyokaishi (Journal of the Ceramic Association, Japan), 68, 223 (1960) Rindone found that a small amount of platinum (0.01%) introduced into a glass of the composition Li20.4SiO2 acts as a nucleating agent on reheating, converting the whole mass into an assembly consisting of extremely small crystals (G. E. Rindone, J. Am. Ceram. Soc., 41, 41 (1958)). This paper presents the results of the investigation of authors which covers the nucleation by platinum for glasses contaning Li 2O, MgO, Al202, and Si02. The bending strength was used for the evaluation of the effect of the nucleating agent. ( 1 ) Optimum amount of platinum. The glasses of the composition, Li20 12.5, K20 2.5, Al202 4, SiO, 81% by weight, added, respectively, with 0, 0.001, 0.01, 0.1% of platinum were formed into the specimens of the size 50 x 5 x 2.5mm. Taking the density increase as a reference the effect of the concentration of platinum on the devitrification of the specimens under a stepwise heat treatment was investigated. It was found out that 0.01% was sufficient for the completion of devitrification. The bending strength of the devitrified specimen increased with increasing platinum content. Taking into consideration of the cost of platinum the authors ( 258 )","PeriodicalId":9502,"journal":{"name":"Bulletin of the Institute for Chemical Research, Kyoto University","volume":"12 1","pages":"258-258"},"PeriodicalIF":0.0000,"publicationDate":"1961-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Mechanicel Strength of Polycrystalline Materials Propuced from Platinum Containing Glasses\",\"authors\":\"M. Tashiro, S. Sakka, M. Wada\",\"doi\":\"10.2109/JCERSJ1950.68.778_223\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"S tive in preventing formation of either of those structural imperfections associated with trapped electrons or positive holes holes. As to the valency changes of cerium ion itself, a small part of trivalent cerium ions was found to loose their electron upon irradiation by the reaction Ce\\\" hu—> [Ce\\\" with positive hole] + e-. Use of Ordinary Plate Glass as a Gamma-Ray Dosimeter Megumi TASHIRO, SUMi0 SAKKA and Naohiro SOGA Yogyo Kyokaishi (Jo urnal of the Ceramic Association, Japan), 68, 191 (1960) The gamma-ray dose rate distribution in a small closed space, 80mm in dia., 110mm in height, was determined by the use of small pieces of ordinary plate glass, 15 x 6 x 1.72mm, as a dosimeter. The technique of the measurement was described. The advantageous features of the glass dosimeter, i. e., its small size, convenient usage, and preciseness in the measurement, were discussed. A brief description of the construction of a small Co-60 irradiator, in which the measurement was made, was appended. Mechanicel Strength of Polycrystalline Materials Propuced from Platinum Containing Glasses Megumi TASHIRO, Sumio SAKKA and Masamichi WADA Yogyo Kyokaishi (Journal of the Ceramic Association, Japan), 68, 223 (1960) Rindone found that a small amount of platinum (0.01%) introduced into a glass of the composition Li20.4SiO2 acts as a nucleating agent on reheating, converting the whole mass into an assembly consisting of extremely small crystals (G. E. Rindone, J. Am. Ceram. Soc., 41, 41 (1958)). This paper presents the results of the investigation of authors which covers the nucleation by platinum for glasses contaning Li 2O, MgO, Al202, and Si02. The bending strength was used for the evaluation of the effect of the nucleating agent. ( 1 ) Optimum amount of platinum. The glasses of the composition, Li20 12.5, K20 2.5, Al202 4, SiO, 81% by weight, added, respectively, with 0, 0.001, 0.01, 0.1% of platinum were formed into the specimens of the size 50 x 5 x 2.5mm. Taking the density increase as a reference the effect of the concentration of platinum on the devitrification of the specimens under a stepwise heat treatment was investigated. It was found out that 0.01% was sufficient for the completion of devitrification. The bending strength of the devitrified specimen increased with increasing platinum content. 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引用次数: 0
摘要
有效地防止与捕获电子或正空穴相关的结构缺陷的形成。对于铈离子本身的价态变化,发现有小部分三价铈离子在辐照后发生Ce" hu - > [Ce"带正空穴]+ e-的反应而失去电子。TASHIRO, SUMi0 SAKKA and Naohiro SOGA Yogyo Kyokaishi(陶瓷协会学报,日本),68,191(1960)在一个小的封闭空间,直径80mm的伽马射线剂量率分布。,高110mm,用15 × 6 × 1.72mm的普通平板玻璃小片作为剂量计测定。介绍了测量方法。讨论了玻璃剂量计体积小、使用方便、测量准确等优点。简要介绍了小型Co-60辐照器的结构,并在其中进行了测量。Megumi TASHIRO, Sumio SAKKA和Masamichi WADA Yogyo Kyokaishi (Journal of the Ceramic Association, Japan), 68, 223 (1960) Rindone发现,在Li20.4SiO2组成的玻璃中加入少量的铂(0.01%)作为再加热的成核剂,将整个质量转化为由极小晶体组成的组装体(G. E. Rindone, J. Am)。陶瓷。Soc。(1958))。本文介绍了作者对含有Li 2O、MgO、Al202和sio2的玻璃的铂成核的研究结果。用抗弯强度来评价成核剂的作用。(1)最佳铂用量。将Li20 12.5、K20 2.5、Al202 4、SiO含量分别为81%(重量比),铂含量分别为0、0.001、0.01、0.1%的玻璃制成尺寸为50 × 5 × 2.5mm的试样。以密度增加为参照,研究了铂浓度对分步热处理试样脱硝的影响。结果表明,0.01%的浓度足以完成脱硝。反氮化试样的抗弯强度随铂含量的增加而增加。考虑到铂的成本,作者(258)
Mechanicel Strength of Polycrystalline Materials Propuced from Platinum Containing Glasses
S tive in preventing formation of either of those structural imperfections associated with trapped electrons or positive holes holes. As to the valency changes of cerium ion itself, a small part of trivalent cerium ions was found to loose their electron upon irradiation by the reaction Ce" hu—> [Ce" with positive hole] + e-. Use of Ordinary Plate Glass as a Gamma-Ray Dosimeter Megumi TASHIRO, SUMi0 SAKKA and Naohiro SOGA Yogyo Kyokaishi (Jo urnal of the Ceramic Association, Japan), 68, 191 (1960) The gamma-ray dose rate distribution in a small closed space, 80mm in dia., 110mm in height, was determined by the use of small pieces of ordinary plate glass, 15 x 6 x 1.72mm, as a dosimeter. The technique of the measurement was described. The advantageous features of the glass dosimeter, i. e., its small size, convenient usage, and preciseness in the measurement, were discussed. A brief description of the construction of a small Co-60 irradiator, in which the measurement was made, was appended. Mechanicel Strength of Polycrystalline Materials Propuced from Platinum Containing Glasses Megumi TASHIRO, Sumio SAKKA and Masamichi WADA Yogyo Kyokaishi (Journal of the Ceramic Association, Japan), 68, 223 (1960) Rindone found that a small amount of platinum (0.01%) introduced into a glass of the composition Li20.4SiO2 acts as a nucleating agent on reheating, converting the whole mass into an assembly consisting of extremely small crystals (G. E. Rindone, J. Am. Ceram. Soc., 41, 41 (1958)). This paper presents the results of the investigation of authors which covers the nucleation by platinum for glasses contaning Li 2O, MgO, Al202, and Si02. The bending strength was used for the evaluation of the effect of the nucleating agent. ( 1 ) Optimum amount of platinum. The glasses of the composition, Li20 12.5, K20 2.5, Al202 4, SiO, 81% by weight, added, respectively, with 0, 0.001, 0.01, 0.1% of platinum were formed into the specimens of the size 50 x 5 x 2.5mm. Taking the density increase as a reference the effect of the concentration of platinum on the devitrification of the specimens under a stepwise heat treatment was investigated. It was found out that 0.01% was sufficient for the completion of devitrification. The bending strength of the devitrified specimen increased with increasing platinum content. Taking into consideration of the cost of platinum the authors ( 258 )