Salen钴(III)叠氮配合物Na[Co(Salen)(N3)2]的晶体结构

M. Weil, A. D. Khalaji
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引用次数: 5

摘要

钴(III)叠氮配合物Na[Co(salen)(N3)2]在扭曲的八面体配位中含有Co(III)阳离子。八面体的赤道面由来自四齿salen配体的两个N和两个O原子定义,轴向配体属于来自两个不同叠氮阴离子的两个末端N原子。通过Na+阳离子与配体的N和O原子之间的相互作用,[Co(salen)(N3)2]-阴离子连接成聚合物结构,形成与[100]平行的波纹带。
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Crystal Structure of the Salen Cobalt(III) Azido Complex Na[Co(salen)(N3)2]
The cobalt(III) azido complex, Na[Co(salen)(N3)2], contains a Co(III) cation in a distorted octahedral coordination. The equatorial plane of the octahedron is defined by two N and two O atoms from the tetradentate salen ligand, and the axial ligands belong to two terminal N atoms from two different azide anions. Via interactions between the Na+ cations and the N and O atoms of the ligands, the [Co(salen)(N3)2]- anions are connected into a polymeric structure, forming corrugated ribbons parallel to [100].
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