{"title":"乙基-1-苯基-2-三甲基硅基-3-氧- 3h -苯并[b]环丁基[d]吡喃-2a(8bH)-羧酸盐的晶体结构","authors":"H. Fun, S. Chantrapromma, Z. Li, Jian-hua Xu","doi":"10.2116/ANALSCIX.24.X49","DOIUrl":null,"url":null,"abstract":"The title compound, C23H24O4Si, was synthesized by photo-induced reactions and characterized by single-crystal X-ray diffraction. The compound crystallizes in the orthorhombic space group Pbca, with a=9.7299(2), b=19.6064(4), c=21.6264(5)A, V=4125.63(15)A3, Z=8 and Dx 1.264 g cm-3. The dihedral angle between the cyclobutene and the attached benzene ring is 38.04(13)°. The molecules are linked into an infinite chain along the a-axis. The crystal structure is stabilized by weak C-H…O and C-H…π interactions.","PeriodicalId":7796,"journal":{"name":"Analytical Sciences: X-ray Structure Analysis Online","volume":"61 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2008-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Crystal Structure of Ethyl-1-phenyl-2-trimethylsilanyl-3-oxo-3H-Benzo[b]cyclobuta[d]pyran-2a(8bH)-carboxylate\",\"authors\":\"H. Fun, S. Chantrapromma, Z. Li, Jian-hua Xu\",\"doi\":\"10.2116/ANALSCIX.24.X49\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The title compound, C23H24O4Si, was synthesized by photo-induced reactions and characterized by single-crystal X-ray diffraction. The compound crystallizes in the orthorhombic space group Pbca, with a=9.7299(2), b=19.6064(4), c=21.6264(5)A, V=4125.63(15)A3, Z=8 and Dx 1.264 g cm-3. The dihedral angle between the cyclobutene and the attached benzene ring is 38.04(13)°. The molecules are linked into an infinite chain along the a-axis. The crystal structure is stabilized by weak C-H…O and C-H…π interactions.\",\"PeriodicalId\":7796,\"journal\":{\"name\":\"Analytical Sciences: X-ray Structure Analysis Online\",\"volume\":\"61 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2008-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Analytical Sciences: X-ray Structure Analysis Online\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2116/ANALSCIX.24.X49\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analytical Sciences: X-ray Structure Analysis Online","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2116/ANALSCIX.24.X49","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
通过光诱导反应合成了标题化合物C23H24O4Si，并用单晶x射线衍射对其进行了表征。化合物在正交空间群Pbca中结晶，a=9.7299(2)， b=19.6064(4)， c=21.6264(5) a, V=4125.63(15)A3, Z=8, Dx为1.264 g cm-3。环丁烯与所附苯环的二面角为38.04(13)°。分子沿着a轴连接成一条无限链。弱的C-H…O和C-H…π相互作用稳定了晶体结构。
Crystal Structure of Ethyl-1-phenyl-2-trimethylsilanyl-3-oxo-3H-Benzo[b]cyclobuta[d]pyran-2a(8bH)-carboxylate
The title compound, C23H24O4Si, was synthesized by photo-induced reactions and characterized by single-crystal X-ray diffraction. The compound crystallizes in the orthorhombic space group Pbca, with a=9.7299(2), b=19.6064(4), c=21.6264(5)A, V=4125.63(15)A3, Z=8 and Dx 1.264 g cm-3. The dihedral angle between the cyclobutene and the attached benzene ring is 38.04(13)°. The molecules are linked into an infinite chain along the a-axis. The crystal structure is stabilized by weak C-H…O and C-H…π interactions.
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