木材用硅酸盐基结构胶粘剂的剪切性能

Dániel Csanády, Olivér Fenyvesi
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引用次数: 0

摘要

在木结构中,许多接缝都使用高分子胶粘剂,工业木材副产品中也含有大量的高分子树脂。这些粘合剂大多是人造聚合物,对环境的影响很大,其中许多对人体健康有负面影响。一些天然或硅酸盐基胶粘剂可用于建筑行业,但其耐热性或耐水性较差。这些类型的粘合剂中的一些已经发展,但化合物含有一些人造聚合物,并且耐热性一般比硅酸盐基差。本文研究了硅酸盐基粘结剂的耐水性和耐热性。为了作为基准,还测试了PVA基工业木材胶粘剂(作为参考)。对粘接接头进行了湿、热两种工况下的抗剪强度测试和比较。用其它硅酸盐、酸或碱对基准硅酸盐基粘结剂进行改性。研究了改性剂对粘合剂溶解度的影响。结果表明,标准粘结剂在正常条件下具有较高的强度,而改性硅酸盐粘结剂在湿热条件下具有较好的性能。改性剂可以在不降低材料耐热性的情况下提高材料的抗剪强度、延展性和耐水性,并使材料质量更加均匀。硅酸盐粘结剂形成了粗糙的粘结面,可以有效地传递试样组分之间的力。
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Shear behaviour of silicate-based structural adhesives for timber
In timber structures, many joints are constructed with polymer adhesives and industrial timber by-products also contain polymer resins in huge amount. Majority of these adhesives are artificial polymers with big environmental footprints and lots of them have a negative effect on human health. Some natural or silicate-based adhesives are available in the construction industry, but their heat or water resistance are poor. Some of these types of adhesives have evolved but compounds contain some artificial polymer, and the heat resistance is worse than silicate-based in general. In this article, water-resistance and heat resistance have been investigated in the case of silicate-based binders. In order to be a benchmark, a PVA based industrial timber adhesive (as reference) was also tested. The shear strength of the bonded joints was tested and compared under wet and hot conditions. Reference silicate-based binder was modified with other silicate, acids or alkalines. The effect of modifiers on the solubility of binders was also investigated. As a result it was stated, that reference binder has a higher strength under normal conditions, but the modified silicate binders have better performance under wet and hot conditions. The modifiers can increase the shear strength, ductility, and water-resistance without decreasing the heat resistance and also makes the material quality more uniform. The silicate binders make a rough bond surface, which can pass the forces effectively between the components of specimens.
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审稿时长
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