GeO2-Cu(II)-NaCl体系在阳离子CRBO2阴离子上的平衡条件、吸附动力学及废柱解吸模式

M. Jafarli, A. Abbasov
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引用次数: 0

摘要

研究了以具有氨基葡萄糖官能团的苯乙烯大分子为螯合剂合成的DIAION CRBO2阴离子的红外光谱。研究了阴离子对锗(IV)-铜(II)- cl -体系的吸附性能。结果表明,阴离子的羟基和氨基与锗酸盐和铜(II)离子的相互作用是以形成相应的配合物为基础的。构造了吸附等温线的各种变体,给出了等温线的计算方程,并在动力学机理的基础上阐明了外扩散、混合扩散和内扩散的作用。测定了所研究组分在处理后的阴离子柱上的解吸模式。
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EQUILIBRIUM CONDITIONS, ADSORPTION KINETICS OF THE GeO2-Cu(II)-NaCl SYSTEM ON DIAION CRBO2 ANIONITE AND DESORPTION MODE FROM SPENT COLUMNS
The IR spectrum of DIAION CRBO2 anionite synthesized on the basis of a chelating agent, a styrene macromolecule with a glucamine functional group, has been studied. Sorption properties of anionite with respect to the germanium(IV)-copper(II)-Cl-system have been studied.. It is shown that the interaction of hydroxyl and amino groups of anionite with germanate and copper(II) ions is based on the formation of corresponding complexes. Various variants of sorption isotherms are constructed, calculation equations are proposed, which are followed by isotherms, the role of external, mixed and internal diffusion on the basis of the kinetic mechanism of processes is clarified.The desorption mode of the studied components from the treated anionite column was determined.
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