电子显微镜、质谱和x射线光谱电子探针微分析仪在生态学和分析研究中的应用。贝加尔湖悬浮物中未知性质蓝色微粒的元素组成

O. Belozerova, V. Egorov, Aleksandr Chebikin, I. B. Mizandrontsev, T. Shishlyannikova, A. Nikonova
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引用次数: 1

摘要

在2018年4月至6月期间,贝加尔湖水中的悬浮物在距离海岸25米(高达4000米)的不同距离内存在蓝色硬颗粒,大小达900公里,性质不明,在近岸区域数量最多,耐矿物酸和燃烧。利用电子显微镜和喷雾镀导电金涂层、电感连接等离子体(质谱)x射线光谱电子探针显微分析仪进行现场解吸分析,以及对研究对象表面和分布在其中的成分进行调查,发现有68种元素进入了颗粒的组成。主要成分为Ti、Ca和Si。高密度金属的成分相对较高:Zn, Pb, Sb, Nb, Cu, As。对蓝色微粒的人为性质作了推测——在钛与船舶涂料复合的基础上,蓝色微粒以钛与发烟相凝聚产物的形式存在,并以吸附剂的形式存在。
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Use of Methods of Electronic Microscopy, Mass-Spectrometry and Roentgenospectral Electronic Probe Micro-Analyzer in Ecological and Analytical Studies. Elemental Composition of Blue Micro-Particles of Unknown Nature Observed in Suspended Substance of Lake Baikal
During the period from April till June, 2018, suspended substance of Baikal Lake water from depths up to 25 meters in various distance from the shore (up to 4,000 m) showed presence of hard particles of blue color in size up to 900 mkm of unknown nature with maximum numbers at the nearshore zone, resistant to mineral acids and combustion. The analysis using methods of electronic microscopy with spray application of conducting golden coating, field desorption with inductively connected plasma (mass-spectroscopy) roentgenospectral electronic probe micro-analyzer, along with investigation of the surfaces of the objects studied and the components distributed in them, showed a set of 68 elements entering the composition of the particles. The major composition is marked for Ti, Ca and Si. Comparatively high composition is found for high-density metals: Zn, Pb, Sb, Nb, Cu, As. Suppositions are made about the anthropogenic nature of the blue particles — in forms of products of agglomerating titanium with fuliginous phase, as well as in composition of sorbents on the basis of compounding of titanium and ship paints.
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