一种新型二维二苯甲酸(H2dpa)锌(II)配合物的合成与结构

Juangang Wang, Rui Shen, Wei-Na Wu, Jincai Wu, N. Tang
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引用次数: 0

摘要

采用水热法制备了一种新型的四面体配位锌聚合物并对其进行了表征。晶型为单斜晶系,空间群为P21/c, a = 12.8437(1) a, b = 5.9596(1) a, c = 17.2934(2) a, β = 104.057(4)°,V = 1284.06(18)A3, Z = 4。标题配合物的结构由扩展的二维双螺旋链组成。
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Synthesis and Structure of a Novel Two-dimensional Diphenic Acid (H2dpa) Zinc(II) Complex
A novel tetrahedral coordinated zinc polymer was hydrothermally prepared and characterized. It was crystallized in the monoclinic system, space group P21/c with a = 12.8437(1)A, b = 5.9596(1)A, c = 17.2934(2)A, β = 104.057(4)°, V = 1284.06(18)A3 and Z = 4. The structure of the title complex consists of extended two-dimensional double helix chains.
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