{"title":"正己烷在硅石-1中的吸附:等均衡方法","authors":"Yiwen Yang, Lovat V.C. Rees","doi":"10.1016/S0927-6513(97)00071-0","DOIUrl":null,"url":null,"abstract":"<div><p>An isosteric method has been used to determine the adsorption equilibrium of hexane in silicalite-1 from 333 K to 423 K, and loadings of 2.8 to 5.5 molecules per unit cell. The isosteric heats of adsorption, <em>q</em><sub>st</sub>, and the differential molar entropies of adsorption, <em>ΔS∘</em>, have been calculated from the isosteres. Isotherms were also obtained from the isosteres. All isotherms show an inflection at a coverage of ~4 molecules per unit cell.</p></div>","PeriodicalId":100926,"journal":{"name":"Microporous Materials","volume":"12 1","pages":"Pages 117-122"},"PeriodicalIF":0.0000,"publicationDate":"1997-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0927-6513(97)00071-0","citationCount":"22","resultStr":"{\"title\":\"Adsorption of normal hexane in silicalite-1: an isosteric approach\",\"authors\":\"Yiwen Yang, Lovat V.C. Rees\",\"doi\":\"10.1016/S0927-6513(97)00071-0\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>An isosteric method has been used to determine the adsorption equilibrium of hexane in silicalite-1 from 333 K to 423 K, and loadings of 2.8 to 5.5 molecules per unit cell. The isosteric heats of adsorption, <em>q</em><sub>st</sub>, and the differential molar entropies of adsorption, <em>ΔS∘</em>, have been calculated from the isosteres. Isotherms were also obtained from the isosteres. All isotherms show an inflection at a coverage of ~4 molecules per unit cell.</p></div>\",\"PeriodicalId\":100926,\"journal\":{\"name\":\"Microporous Materials\",\"volume\":\"12 1\",\"pages\":\"Pages 117-122\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1997-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S0927-6513(97)00071-0\",\"citationCount\":\"22\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Microporous Materials\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0927651397000710\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Microporous Materials","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0927651397000710","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 22
摘要
用等均衡法测定了硅石-1在333 K ~ 423 K、2.8 ~ 5.5分子/胞的负载范围内的吸附平衡。等容吸附热qst和吸附微分摩尔熵ΔS°都是由等容体计算出来的。从同分异构体也得到了等温线。所有的等温线在每细胞覆盖约4个分子时都有一个拐点。
Adsorption of normal hexane in silicalite-1: an isosteric approach
An isosteric method has been used to determine the adsorption equilibrium of hexane in silicalite-1 from 333 K to 423 K, and loadings of 2.8 to 5.5 molecules per unit cell. The isosteric heats of adsorption, qst, and the differential molar entropies of adsorption, ΔS∘, have been calculated from the isosteres. Isotherms were also obtained from the isosteres. All isotherms show an inflection at a coverage of ~4 molecules per unit cell.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
