铌基Ti-Si涂层的耐热性及相组成

A. Kasatkin, S. U. Rybakov, G. M. Anurova
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摘要

热冲击下耐火材料的扩散硅化物涂层。提高其耐久性的一个有前景的方法是形成多组分涂层。钛是这类涂层中广泛使用的成分之一。本文研究了钛和硅在混合粉末中同时扩散饱和铌的过程。该涂层可分为两种基本类型:铌钛固溶体和铌钛硅化物。第一类涂层是由ti - ti5si3粉末混合物制成的。在硅活性较高的填料(ti5si3 -TiSi和tisi2 -TiSi混合物)中观察到复杂的硅化物层。钛和硅的活性是镀层相组成的主要控制因素。涂层允许增加铌和铌合金的耐热性高达2000°C(1.5小时)。
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Heat-Resistance and Phase Composition of Ti-Si Coatings on Niobium
A diffusion silicide coatings on refractory under thermal shock. A prospective method of improving their durability is the formation of multi-component coatings. Ti is one of the widespread oomponents of such coatings. In this work, process of simultaneous diffusion saturation of niobium by Ti and Si in powder mixtures has been investigated. The coatings can be divided into two basic types: Nb-Ti solid solutions and Nb and Ti silicides. The coatings of the first type obtained in Ti-Ti 5 Si 3 powder mixtures. The complex silicide layers were observed in the packs with higher silicon aotivity (Ti 5 Si 3 -TiSi and TiSi 2 -TiSi mixtures). The activities of Ti and Si have been shown to be principal controlling factors in coating phase in composition. The coatings allows to increase heat-resistance of the niobium and niobium alloys up to 2000°C (1,5 hour).
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