由聚(6,8-(1,5-二氯-2,4-二氧基-3-酮)-双环[3.3.0]辛基乙烯基)合成聚(4,5-二羟基-1,3-环戊二烯乙烯基)。前驱体聚合物水解生成共轭聚合物

British Polymer Journal Pub Date : 1986-05-01 DOI:10.1002/PI.4980180305

W. Feast, Kevin Harper

引用次数: 4

摘要

聚(6,8-(1,5-二氯-2,4-二氧二氧-3-酮)双环[3.3.0]辛基乙烯基)水解生成聚(4,5-二羟基-1,3-环戊二烯基乙烯基)，这是一种新的共轭聚合物。这种新体系可以作为其前驱体聚合物的表面层生成。利用红外光谱、光谱学、元素分析、显微镜和电导率测量等方法研究了转化过程。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Synthesis of poly(4,5-bis-hydroxy-1,3-cyclopentadienylene vinylene) from poly(6,8-(1,5-dichloro-2,4-dioxa-3-keto)-bicyclo [3.3.0] octylene vinylene). Generation of a conjugated polymer by hydrolysis of a precursor polymer

Hydrolysis of poly(6,8-(1,5-dichloro-2,4-dioxa-3-keto)bicyclo[3.3.0]octylene vinylene) results in the formation of poly(4,5-bis-hydroxy-1,3-cyclopentadienylene vinylene), a new conjugated polymer. This new system can be generated as a surface layer on its precursor polymer. The conversion process has been studied with the aid of infrared and optical spectroscopy, elemental analysis, microscopy and conductivity measurements.

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British Polymer Journal

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