{"title":"合成和单晶x射线结构的第一个例子，三齿，二正金属化亚磷酸三苯基配合物","authors":"R. Bedford, P. A. Chaloner, P. Hitchcock","doi":"10.1039/C39950002049","DOIUrl":null,"url":null,"abstract":"Reaction of [Ir(cod)(py)2][PF6] with triphenyl phosphite leads to the previously reported complex [Ir(cod){P(OC6H4)(OPh)2{P(OPh)3}], but reaction of [Ir(cod){P(OPh)3}Cl] with methyllithium and subsequent treatment with methanol yields the tridentate di-orthometallated complex [IrH(cod){P(OC6H4)2(OPh)}].","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":"4 1","pages":"2049-2050"},"PeriodicalIF":0.0000,"publicationDate":"1995-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"7","resultStr":"{\"title\":\"The synthesis and single-crystal X-ray structure of the first example of a tridentate, di-orthometallated triphenyl phosphite complex\",\"authors\":\"R. Bedford, P. A. Chaloner, P. Hitchcock\",\"doi\":\"10.1039/C39950002049\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Reaction of [Ir(cod)(py)2][PF6] with triphenyl phosphite leads to the previously reported complex [Ir(cod){P(OC6H4)(OPh)2{P(OPh)3}], but reaction of [Ir(cod){P(OPh)3}Cl] with methyllithium and subsequent treatment with methanol yields the tridentate di-orthometallated complex [IrH(cod){P(OC6H4)2(OPh)}].\",\"PeriodicalId\":17282,\"journal\":{\"name\":\"Journal of The Chemical Society, Chemical Communications\",\"volume\":\"4 1\",\"pages\":\"2049-2050\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1995-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"7\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society, Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C39950002049\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950002049","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The synthesis and single-crystal X-ray structure of the first example of a tridentate, di-orthometallated triphenyl phosphite complex
Reaction of [Ir(cod)(py)2][PF6] with triphenyl phosphite leads to the previously reported complex [Ir(cod){P(OC6H4)(OPh)2{P(OPh)3}], but reaction of [Ir(cod){P(OPh)3}Cl] with methyllithium and subsequent treatment with methanol yields the tridentate di-orthometallated complex [IrH(cod){P(OC6H4)2(OPh)}].
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