现代思想背景下的共轭反应理论

T. Nagiev
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引用次数: 2

摘要

讨论了反应之间各种可能的相互作用。它们中的一些是由化学反应干扰的一般概念统一起来的。拓宽了共轭反应的思路,推导了共轭反应的行列式;建立了化学干涉的相干条件,并确定了相关的相移。它显示了如何定性和定量地评估反应之间的相互作用,以及如何在同时考虑固定浓度法的情况下,对机理尚未研究的复杂反应进行动力学分析。通过具体的例子,考虑了过氧化氢解离和底物氧化的干扰。
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The Theory of Conjugate Reactions in the Context of Modern Ideas
Various types of possible interactions between reactions are discussed. Some of them are united by the general idea of chemical reaction interference. The ideas on conjugated reactions are broadened and the determinant formula is deduced; the coherence condition for chemical interference is formulated and associated phase shifts are determined. It is shown how interaction between reactions may be qualitatively and quantitatively assessed and kinetic analysis of complex reactions with under-researched mechanisms may be performed with simultaneous consideration of the stationary concentration method. Using particular examples, interference of hydrogen peroxide dissociation and oxidation of substrates is considered.
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