CaCO3和增容剂SMA-2025对CaCO3/PLA/PBAT形状记忆复合材料性能的影响

Laiming Yu, Yaqin Fu, Yubing Dong
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引用次数: 0

摘要

摘要为了提高聚乳酸/聚己二酸丁酯-对苯二甲酸酯(PLA/PBAT)复合材料的力学性能和加工性能,降低其成本,在PLA/PBAT体系中加入碳酸钙(CaCO3)和增塑剂苯乙烯-马来酸酐共聚物(SMA-2025),研究CaCO3和SMA-2025对PLA/PBAT体系的形貌、结构、力学性能、热性能的影响。对CaCO3/PLA/PBAT复合材料的热稳定性和形状记忆性能进行了研究和讨论。采用熔融共混和热压法制备了CaCO3/PLA/PBAT形状记忆复合材料,并分别通过扫描电镜、通用测试仪、傅里叶变换红外光谱、差示扫描量热法、热重分析和DMA等手段研究了CaCO3和SMA-2025对复合材料性能的影响。结果CaCO3和SMA-2025的加入显著改善了CaCO3/PLA/PBAT形状记忆复合材料的界面性能、力学性能、热稳定性、形状记忆恢复率、恢复应力和加工性能。CaCO3/PLA/PBAT复合材料具有良好的吹膜加工性能。独创性/价值本研究将为高性能CaCO3/PLA/PBAT形状记忆复合材料的研究、加工和应用提供参考。
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Effect of CaCO3 and compatibilizer SMA-2025 on the property of CaCO3/PLA/PBAT shape memory composites
Purpose The purpose of this study is to improve the mechanical property and processing performance and reduce the cost of the polylacticacid/polybutyleneadipate-co-terephthalate(PLA/PBAT) composites, the calcium carbonate (CaCO3) and compatibilizer styrene-maleicanhydride copolymer (SMA-2025) were added to the PLA/PBAT system, and the effect of CaCO3 and SMA-2025 on the morphology, structure, mechanical property, thermal property, thermalstability and shape memory property of the CaCO3/PLA/PBAT composites were studied and discussed. Design/methodology/approach The CaCO3/PLA/PBAT shape memory composites were prepared via melt-blending and hot-pressing methods, and the effect of CaCO3 and SMA-2025 on the property of the composites was investigated via scanning electron microscope, universal testing instrument, Fourier transform infrared spectroscopy, differential scanning calorimetry, thermogravimetric analysis and DMA, respectively. Findings The interface property, mechanical property, thermal stability, shape memory recovery ratios and recovery stresses, and processing performance of the CaCO3/PLA/PBAT shape memory composites were significantly improved by adding of CaCO3 and SMA-2025. Moreover, the CaCO3/PLA/PBAT composites have good blowing film processing performance. Originality/value This study will provide a reference for the research, processing and application of the high-performance CaCO3/PLA/PBAT shape memory composites.
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