{"title":"锌(II)混合配合物的立体选择性和激子棉效应","authors":"S. Bunel ∗, G. Larrazábal, A. Decinti","doi":"10.1016/0022-1902(81)80616-1","DOIUrl":null,"url":null,"abstract":"<div><p>Mixed complexes of Zn(II) with chiral aminoacids and 1,10-phenanthroline have been prepared and their C.D. and O.R.D. spectra measured. All the C.D. spectra exhibited an exciton splitting at 268 nm and their intensities depended on the chiral ligand. These results were interpreted in terms of steric effects through the exciton theory.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 11","pages":"Pages 2781-2783"},"PeriodicalIF":0.0000,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80616-1","citationCount":"5","resultStr":"{\"title\":\"Stereoselectivity and exciton cotton effects in mixed complexes of zinc(II)\",\"authors\":\"S. Bunel ∗, G. Larrazábal, A. Decinti\",\"doi\":\"10.1016/0022-1902(81)80616-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Mixed complexes of Zn(II) with chiral aminoacids and 1,10-phenanthroline have been prepared and their C.D. and O.R.D. spectra measured. All the C.D. spectra exhibited an exciton splitting at 268 nm and their intensities depended on the chiral ligand. These results were interpreted in terms of steric effects through the exciton theory.</p></div>\",\"PeriodicalId\":16275,\"journal\":{\"name\":\"Journal of Inorganic and Nuclear Chemistry\",\"volume\":\"43 11\",\"pages\":\"Pages 2781-2783\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1981-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0022-1902(81)80616-1\",\"citationCount\":\"5\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Inorganic and Nuclear Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0022190281806161\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Inorganic and Nuclear Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0022190281806161","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Stereoselectivity and exciton cotton effects in mixed complexes of zinc(II)
Mixed complexes of Zn(II) with chiral aminoacids and 1,10-phenanthroline have been prepared and their C.D. and O.R.D. spectra measured. All the C.D. spectra exhibited an exciton splitting at 268 nm and their intensities depended on the chiral ligand. These results were interpreted in terms of steric effects through the exciton theory.
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