mof材料(CuOBA)在5′-溴-2′-羟基苯乙酮与苯醚反应中的应用

H. Nguyen, Thao T. Nguyen
{"title":"mof材料(CuOBA)在5′-溴-2′-羟基苯乙酮与苯醚反应中的应用","authors":"H. Nguyen, Thao T. Nguyen","doi":"10.35382/18594816.1.33.2019.140","DOIUrl":null,"url":null,"abstract":"The metal organic frameworks material (CuOBA) was synthesized by solvothermal method. The physicochemical characteristics of this solid catalyst  were  determined by a number of different analytical techniques including X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron  microscopy (TEM), thermogravimetric analysis (TGA), and Fourier transform infrared (FT-IR). The CuOBA was used as a heterogeneous catalyst for the coupling reaction of C=O connection between 5’- bromo - 2’-hydroxiacetophenone and benzyl ether in good conversion. The effects of time, temperature, concentration of reactants, solvents, and mass of catalyst were surveyed. The results revealed that CuOBA is used as a catalyst for organic reactions with conversion of 87%, and the solid catalyst could be recovered six times without a significant degradation in catalytic activity.","PeriodicalId":21692,"journal":{"name":"Scientific Journal of Tra Vinh University","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2019-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"APPLICATIONS OF MOFs MATERIALS (CuOBA) AS A CATALYST FOR REACTION OF 5’-BROMO-2’-HYDROXIACETOPHENONE AND BENZYL ETHER\",\"authors\":\"H. Nguyen, Thao T. Nguyen\",\"doi\":\"10.35382/18594816.1.33.2019.140\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The metal organic frameworks material (CuOBA) was synthesized by solvothermal method. The physicochemical characteristics of this solid catalyst  were  determined by a number of different analytical techniques including X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron  microscopy (TEM), thermogravimetric analysis (TGA), and Fourier transform infrared (FT-IR). The CuOBA was used as a heterogeneous catalyst for the coupling reaction of C=O connection between 5’- bromo - 2’-hydroxiacetophenone and benzyl ether in good conversion. The effects of time, temperature, concentration of reactants, solvents, and mass of catalyst were surveyed. The results revealed that CuOBA is used as a catalyst for organic reactions with conversion of 87%, and the solid catalyst could be recovered six times without a significant degradation in catalytic activity.\",\"PeriodicalId\":21692,\"journal\":{\"name\":\"Scientific Journal of Tra Vinh University\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2019-07-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Scientific Journal of Tra Vinh University\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.35382/18594816.1.33.2019.140\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Scientific Journal of Tra Vinh University","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.35382/18594816.1.33.2019.140","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

采用溶剂热法合成了金属有机骨架材料(CuOBA)。通过x射线粉末衍射(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、热重分析(TGA)和傅里叶变换红外(FT-IR)等多种分析技术测定了该固体催化剂的物理化学特性。将CuOBA作为非均相催化剂,用于5′-溴- 2′-羟基苯乙酮与苯醚的C=O连接偶联反应,转化率良好。考察了时间、温度、反应物浓度、溶剂、催化剂质量等因素对反应的影响。结果表明,CuOBA作为有机反应的催化剂,转化率为87%,固体催化剂可回收6次,催化活性没有明显下降。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
APPLICATIONS OF MOFs MATERIALS (CuOBA) AS A CATALYST FOR REACTION OF 5’-BROMO-2’-HYDROXIACETOPHENONE AND BENZYL ETHER
The metal organic frameworks material (CuOBA) was synthesized by solvothermal method. The physicochemical characteristics of this solid catalyst  were  determined by a number of different analytical techniques including X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron  microscopy (TEM), thermogravimetric analysis (TGA), and Fourier transform infrared (FT-IR). The CuOBA was used as a heterogeneous catalyst for the coupling reaction of C=O connection between 5’- bromo - 2’-hydroxiacetophenone and benzyl ether in good conversion. The effects of time, temperature, concentration of reactants, solvents, and mass of catalyst were surveyed. The results revealed that CuOBA is used as a catalyst for organic reactions with conversion of 87%, and the solid catalyst could be recovered six times without a significant degradation in catalytic activity.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
期刊最新文献
STUDY ON THE QUALITY PARAMETERS OF POND APPLE JAM (Annona glabra L.) FACTORS AFFECTING THE QUALITY OF WOOD APPLE LIQUOR (Limonia acidissima L.) STUDENT’S EVALUATION ON FACTORS INFLUENCING DECISIONS OF MAJORING IN HOTEL MANAGEMENT AT KIEN GIANG COLLEGE EFFECTS OF EXTRACTS FROM LEAVES AND ROOTS OF Melaleuca cajuputi Powell ON NEMATODES CAUSING DISEASES ON Piper nigrum L. (BLACK PEPPER) IN VITRO BANH PHCHUMBÂN, SEN ĐÔNTA FESTIVAL OF VIETNAM SOUTHERN KHMER: TRADITIONS AND MODERN CHANGES
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1