mof材料(CuOBA)在5′-溴-2′-羟基苯乙酮与苯醚反应中的应用

H. Nguyen, Thao T. Nguyen
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引用次数: 0

摘要

采用溶剂热法合成了金属有机骨架材料(CuOBA)。通过x射线粉末衍射(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、热重分析(TGA)和傅里叶变换红外(FT-IR)等多种分析技术测定了该固体催化剂的物理化学特性。将CuOBA作为非均相催化剂,用于5′-溴- 2′-羟基苯乙酮与苯醚的C=O连接偶联反应,转化率良好。考察了时间、温度、反应物浓度、溶剂、催化剂质量等因素对反应的影响。结果表明,CuOBA作为有机反应的催化剂,转化率为87%,固体催化剂可回收6次,催化活性没有明显下降。
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APPLICATIONS OF MOFs MATERIALS (CuOBA) AS A CATALYST FOR REACTION OF 5’-BROMO-2’-HYDROXIACETOPHENONE AND BENZYL ETHER
The metal organic frameworks material (CuOBA) was synthesized by solvothermal method. The physicochemical characteristics of this solid catalyst  were  determined by a number of different analytical techniques including X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron  microscopy (TEM), thermogravimetric analysis (TGA), and Fourier transform infrared (FT-IR). The CuOBA was used as a heterogeneous catalyst for the coupling reaction of C=O connection between 5’- bromo - 2’-hydroxiacetophenone and benzyl ether in good conversion. The effects of time, temperature, concentration of reactants, solvents, and mass of catalyst were surveyed. The results revealed that CuOBA is used as a catalyst for organic reactions with conversion of 87%, and the solid catalyst could be recovered six times without a significant degradation in catalytic activity.
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