{"title":"钯催化交偶联在农用化学品合成中的应用","authors":"Yuxin Zhu , Wenfeng Dong , Wenjun Tang","doi":"10.1016/j.aac.2022.11.004","DOIUrl":null,"url":null,"abstract":"<div><p>Palladium-catalyzed cross-couplings have played an increasingly important role in the synthesis of agrochemicals. In this review, the applications of palladium-catalyzed Heck reaction, Suzuki-Miyaura cross-coupling, Sonogashira coupling, Negishi cross-coupling, carbonylation, and Buchwald-Hartwig amination, in the synthesis of agrochemicals are summarized with particular emphasis on catalyst system and catalytic efficiencies. In addition, strategies and advances on ligand development in achieving high TONs for palladium-catalyzed cross-couplings applicable in agrochemical industry are discussed.</p></div>","PeriodicalId":100027,"journal":{"name":"Advanced Agrochem","volume":"1 2","pages":"Pages 125-138"},"PeriodicalIF":0.0000,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2773237122000259/pdfft?md5=676a44d666d945f2d1425e3d017f98c1&pid=1-s2.0-S2773237122000259-main.pdf","citationCount":"4","resultStr":"{\"title\":\"Palladium-catalyzed cross-couplings in the synthesis of agrochemicals\",\"authors\":\"Yuxin Zhu , Wenfeng Dong , Wenjun Tang\",\"doi\":\"10.1016/j.aac.2022.11.004\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Palladium-catalyzed cross-couplings have played an increasingly important role in the synthesis of agrochemicals. In this review, the applications of palladium-catalyzed Heck reaction, Suzuki-Miyaura cross-coupling, Sonogashira coupling, Negishi cross-coupling, carbonylation, and Buchwald-Hartwig amination, in the synthesis of agrochemicals are summarized with particular emphasis on catalyst system and catalytic efficiencies. In addition, strategies and advances on ligand development in achieving high TONs for palladium-catalyzed cross-couplings applicable in agrochemical industry are discussed.</p></div>\",\"PeriodicalId\":100027,\"journal\":{\"name\":\"Advanced Agrochem\",\"volume\":\"1 2\",\"pages\":\"Pages 125-138\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2773237122000259/pdfft?md5=676a44d666d945f2d1425e3d017f98c1&pid=1-s2.0-S2773237122000259-main.pdf\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Agrochem\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2773237122000259\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Agrochem","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2773237122000259","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Palladium-catalyzed cross-couplings in the synthesis of agrochemicals
Palladium-catalyzed cross-couplings have played an increasingly important role in the synthesis of agrochemicals. In this review, the applications of palladium-catalyzed Heck reaction, Suzuki-Miyaura cross-coupling, Sonogashira coupling, Negishi cross-coupling, carbonylation, and Buchwald-Hartwig amination, in the synthesis of agrochemicals are summarized with particular emphasis on catalyst system and catalytic efficiencies. In addition, strategies and advances on ligand development in achieving high TONs for palladium-catalyzed cross-couplings applicable in agrochemical industry are discussed.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
