Юрий Александрович Сидоренко, Е. Агабеков, Константин Петрович Волчо, Ф. Салахутдинов, Д. Ю. Мурзин, A. Sidorenko, A. V. Agabekov, K. Volcho, N. Salakhutdinov, D. Murzin
{"title":"在高岭土纳米催化剂存在下，以3-芳烃为原料制备手性偶氮苯并呋喃","authors":"Юрий Александрович Сидоренко, Е. Агабеков, Константин Петрович Волчо, Ф. Салахутдинов, Д. Ю. Мурзин, A. Sidorenko, A. V. Agabekov, K. Volcho, N. Salakhutdinov, D. Murzin","doi":"10.29235/1561-8323-2020-64-4-426-430","DOIUrl":null,"url":null,"abstract":"The reaction of a 2-carene containing mixture, obtained by 3-carene isomerization, with 4-methoxybenzaldehyde in the presence of halloysite nanotubes treated with 5.0 % HCl was studied. The main reaction products are the chiral derivatives of isobenzofuran. Selectivity to these compounds (71.4 %) is comparable to that when only 2-carene is used as a reactant. Thus, the possibility is shown how to use halloysite nanocatalysts for selective production of isobenzofuran compounds based on 3-сarene isomerization products (major component of turpentine) without preliminary mixture separation.","PeriodicalId":11283,"journal":{"name":"Doklady of the National Academy of Sciences of Belarus","volume":"14 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2020-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation of chiral izobenzofuranes based on 3-carene in the presence of halloysite nanocatalysts\",\"authors\":\"Юрий Александрович Сидоренко, Е. Агабеков, Константин Петрович Волчо, Ф. Салахутдинов, Д. Ю. Мурзин, A. Sidorenko, A. V. Agabekov, K. Volcho, N. Salakhutdinov, D. Murzin\",\"doi\":\"10.29235/1561-8323-2020-64-4-426-430\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The reaction of a 2-carene containing mixture, obtained by 3-carene isomerization, with 4-methoxybenzaldehyde in the presence of halloysite nanotubes treated with 5.0 % HCl was studied. The main reaction products are the chiral derivatives of isobenzofuran. Selectivity to these compounds (71.4 %) is comparable to that when only 2-carene is used as a reactant. Thus, the possibility is shown how to use halloysite nanocatalysts for selective production of isobenzofuran compounds based on 3-сarene isomerization products (major component of turpentine) without preliminary mixture separation.\",\"PeriodicalId\":11283,\"journal\":{\"name\":\"Doklady of the National Academy of Sciences of Belarus\",\"volume\":\"14 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2020-08-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Doklady of the National Academy of Sciences of Belarus\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.29235/1561-8323-2020-64-4-426-430\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Doklady of the National Academy of Sciences of Belarus","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.29235/1561-8323-2020-64-4-426-430","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Preparation of chiral izobenzofuranes based on 3-carene in the presence of halloysite nanocatalysts
The reaction of a 2-carene containing mixture, obtained by 3-carene isomerization, with 4-methoxybenzaldehyde in the presence of halloysite nanotubes treated with 5.0 % HCl was studied. The main reaction products are the chiral derivatives of isobenzofuran. Selectivity to these compounds (71.4 %) is comparable to that when only 2-carene is used as a reactant. Thus, the possibility is shown how to use halloysite nanocatalysts for selective production of isobenzofuran compounds based on 3-сarene isomerization products (major component of turpentine) without preliminary mixture separation.
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