共价三嗪聚合物在催化有机转化中的应用

A. Raza, S. Ravi, S. Tajudeen, K. I. Sheriff
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引用次数: 1

摘要

在多孔有机聚合物中,共价三嗪聚合物(ctp)已成为一类重要的材料,在能量储存和转化、气体吸附和分离、光催化和多相催化等方面具有广泛的应用。特别是,ctp由于其优异的热稳定性和化学稳定性以及在催化反应中的可回收性,经常被用作催化剂/催化剂载体。此外,可用于合成ctp的扩展方法,方便的功能化和框架中氮位点的存在使其成为开发有机转化催化剂的合适候选者。本文综述了ctp的合成方法、表征及其在有机转化中作为催化剂/催化剂载体的应用。
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Applications of Covalent Triazine Polymers in Catalytic Organic Transformations
Among the porous organic polymers, Covalent Triazine Polymers (CTPs) have emerged as an important class of materials with versatile applications such as energy storage and conversion, gas adsorption and separation, photocatalysis and heterogeneous catalysis. Particularly, CTPs have been often used as catalyst/catalyst support due to their excellent thermal and chemical stability, as well as recyclability in catalytic reactions. Moreover, the expanding methods available for the synthesis of CTPs, convenient functionalization and presence of nitrogen sites in the framework make them a suitable candidate to develop catalysts for organic transformations. In this review, the methods of synthesis, characterization of CTPs and mainly their applications as catalyst/catalyst support in organic transformations are summarized.
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