{"title":"3,3′-二硝胺基-4,4′-偶氮呋咱二胍盐的合成、晶体结构及性能","authors":"许诚, 毕福强, 张敏, 葛忠学, 刘庆","doi":"10.11943/J.ISSN.1006-9941.2015.02.017","DOIUrl":null,"url":null,"abstract":"以二氨基呋咱(DAF)为原料，经氧化、硝化、复分解反应，合成出3, 3′-二硝胺基-4, 4′-偶氮呋咱二胍盐(G 2 DNAAF)，总收率为64%。采用核磁共振谱、红外光谱、元素分析和X-射线单晶衍射分析对其结构进行了表征。结果表明：G 2 DNAAF属于单斜晶系，空间群 P 2(1)/ n ， a =5.226(2) A, b =12.686(5) A, c =11.944(5) A, α =90°, β =92.896(7)°, γ =90°, V =790.8(5) A 3 , Z =2, D c =1.698 g·cm -3 , μ =0.148 mm -1 , F (000)=416。差示扫描量热分析表明G 2 DNAAF的热分解峰温为259.0 ℃。Gaussian 09和Kamlet-Jacbos公式计算结果表明，G 2 DNAAF的固相生成焓为588.27 kJ·mol -1 ，爆速为7.839 km·s -1 ，爆压为26.81 GPa。","PeriodicalId":35753,"journal":{"name":"Hanneng Cailiao/Chinese Journal of Energetic Materials","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2015-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"3,3′-二硝胺基-4,4′-偶氮呋咱二胍盐的合成、晶体结构及性能\",\"authors\":\"许诚, 毕福强, 张敏, 葛忠学, 刘庆\",\"doi\":\"10.11943/J.ISSN.1006-9941.2015.02.017\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"以二氨基呋咱(DAF)为原料，经氧化、硝化、复分解反应，合成出3, 3′-二硝胺基-4, 4′-偶氮呋咱二胍盐(G 2 DNAAF)，总收率为64%。采用核磁共振谱、红外光谱、元素分析和X-射线单晶衍射分析对其结构进行了表征。结果表明：G 2 DNAAF属于单斜晶系，空间群 P 2(1)/ n ， a =5.226(2) A, b =12.686(5) A, c =11.944(5) A, α =90°, β =92.896(7)°, γ =90°, V =790.8(5) A 3 , Z =2, D c =1.698 g·cm -3 , μ =0.148 mm -1 , F (000)=416。差示扫描量热分析表明G 2 DNAAF的热分解峰温为259.0 ℃。Gaussian 09和Kamlet-Jacbos公式计算结果表明，G 2 DNAAF的固相生成焓为588.27 kJ·mol -1 ，爆速为7.839 km·s -1 ，爆压为26.81 GPa。\",\"PeriodicalId\":35753,\"journal\":{\"name\":\"Hanneng Cailiao/Chinese Journal of Energetic Materials\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2015-02-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Hanneng Cailiao/Chinese Journal of Energetic Materials\",\"FirstCategoryId\":\"1087\",\"ListUrlMain\":\"https://doi.org/10.11943/J.ISSN.1006-9941.2015.02.017\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"Engineering\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Hanneng Cailiao/Chinese Journal of Energetic Materials","FirstCategoryId":"1087","ListUrlMain":"https://doi.org/10.11943/J.ISSN.1006-9941.2015.02.017","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Engineering","Score":null,"Total":0}
引用次数: 0
摘要
以二氨基呋咱(DAF)为原料，经氧化、硝化、复分解反应，合成出3, 3′-二硝胺基-4, 4′-偶氮呋咱二胍盐(G 2 DNAAF)，总收率为64%。采用核磁共振谱、红外光谱、元素分析和X-射线单晶衍射分析对其结构进行了表征。结果表明：G 2 DNAAF属于单斜晶系，空间群 P 2(1)/ n ， a =5.226(2) A, b =12.686(5) A, c =11.944(5) A, α =90°, β =92.896(7)°, γ =90°, V =790.8(5) A 3 , Z =2, D c =1.698 g·cm -3 , μ =0.148 mm -1 , F (000)=416。差示扫描量热分析表明G 2 DNAAF的热分解峰温为259.0 ℃。Gaussian 09和Kamlet-Jacbos公式计算结果表明，G 2 DNAAF的固相生成焓为588.27 kJ·mol -1 ，爆速为7.839 km·s -1 ，爆压为26.81 GPa。
以二氨基呋咱(DAF)为原料，经氧化、硝化、复分解反应，合成出3, 3′-二硝胺基-4, 4′-偶氮呋咱二胍盐(G 2 DNAAF)，总收率为64%。采用核磁共振谱、红外光谱、元素分析和X-射线单晶衍射分析对其结构进行了表征。结果表明：G 2 DNAAF属于单斜晶系，空间群 P 2(1)/ n ， a =5.226(2) A, b =12.686(5) A, c =11.944(5) A, α =90°, β =92.896(7)°, γ =90°, V =790.8(5) A 3 , Z =2, D c =1.698 g·cm -3 , μ =0.148 mm -1 , F (000)=416。差示扫描量热分析表明G 2 DNAAF的热分解峰温为259.0 ℃。Gaussian 09和Kamlet-Jacbos公式计算结果表明，G 2 DNAAF的固相生成焓为588.27 kJ·mol -1 ，爆速为7.839 km·s -1 ，爆压为26.81 GPa。
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