基于EVA和再生地面轮胎橡胶的热塑性弹性体动态阻尼性能研究

IF 1.4 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Journal of Elastomers and Plastics Pub Date : 2011-03-16 DOI:10.1177/0095244311398631
N. Roche, M. Ichchou, M. Salvia, A. Chettah
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引用次数: 28

摘要

回收废旧轮胎对经济和环境都很重要,磨碎的轮胎橡胶可以与其他聚合物混合,改变它们的性能。为了描述和解释这些变化,进行了一项实验研究,研究了在弹性基体(乙烯乙酸乙烯酯,EVA)中添加再生地面轮胎橡胶(GTR)填料对动态阻尼性能的改善。为了评估GTR和孔隙率对GTR/EVA复合材料的影响,通过注射法制备了三种样品:单独的EVA基体、GTR/EVA复合材料和GTR/EVA多孔复合材料。采用动态机械热分析对样品进行动态测量。这些材料的杨氏模量和损耗因子是使用Williams-Landel-Ferry引入的频率-温度等效来估计的,该等效扩展了在更宽频率范围内动态特性的测量。该方法表明,在低频带宽下,通过在EVA矩阵中加入GTR,损耗因子得到了改善。α-弛豫研究表明,两种GTR填充的复合材料的活化能都较低,从而得出GTR的加入提高了聚合物链的迁移率的结论。通过失重试验进行的冲击行为研究也得出结论:gtr填充复合材料的冲击能吸收效果更好,但最大位移要更大。
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Dynamic Damping Properties of Thermoplastic Elastomers Based on EVA and Recycled Ground Tire Rubber
Recycling waste tires being important for both economical and environmental reasons, ground tire rubber can be blended with other polymers, modifying their properties. In order to characterize and explain these modifications, an experimental study was carried out concerning the improvement in the dynamic damping properties when adding recycled ground tire rubber (GTR) fillers to an elastomeric matrix (ethylene vinyl acetate, EVA).To evaluate the influence of both the GTR and the porosity in a GTR/ EVA composite, three samples have been elaborated by injection:the EVA matrix alone, a GTR/EVA composite, and a GTR/EVA porous composite. Dynamic measurements of the samples were performed using dynamic mechanical thermal analysis. The Young’s modulus and loss factor of these materials are estimated using the frequency—temperature equivalence introduced by Williams—Landel—Ferry expanding the measurement of the dynamic properties over a wider range of frequencies. This method showed that in low-frequency bandwidth, the loss factor has been improved by the addition of GTR to the EVA matrix. The α-relaxation study showed lower activation energy for both the GTR-filled composites leading to the conclusion that the mobility of the polymer chains has been improved by addition of GTR. The impact behavior study carried out using a weight drop test experiment also concluded to better impact energy absorption for the GTR-filled composites at the expense of a larger maximum displacement.
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来源期刊
Journal of Elastomers and Plastics
Journal of Elastomers and Plastics 工程技术-材料科学:综合
CiteScore
3.30
自引率
5.90%
发文量
41
审稿时长
6 months
期刊介绍: The Journal of Elastomers and Plastics is a high quality peer-reviewed journal which publishes original research on the development and marketing of elastomers and plastics and the area in between where the characteristics of both extremes are apparent. The journal covers: advances in chemistry, processing, properties and applications; new information on thermoplastic elastomers, reinforced elastomers, natural rubbers, blends and alloys, and fillers and additives.
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