Treatment of black copper with the use of iron scrap - part I

Currently, there is a large amount of mineral resources not being exploited in large copper minings, a clear example are black copper minerals. These resources are generally not incorpo-rated into the extraction circuits or are not treated, either in stocks, leach pads, or debris. These exotic minerals have considerable amounts of Cu and Mn, which are commercially very attractive. They are refractory to conventional leaching processes, therefore, the use of reducing agents is necessary for treatment of these minerals in order to dissolve the present MnO2, which in turn allows Cu extraction. In this research, iron scrap Fe0 was used as a reducing agent for the dissolution of Mn from a black copper mineral in an acidic medium and compared to previous studies of the use of Fe2+ under the same conditions. In addition, the effects of a pretreatment process (agglomeration and curing) by adding NaCl are investigated in order to favor the reduction of MnO2. Finally, it was discovered that there is a higher kinetics of dissolution of Mn when working with Fe0 in short periods of time, although similar extraction efficiencies are obtained after prolonged times. The pretreatment process by adding NaCl resulted in increased Mn extraction in short periods of time (30 min). At applying high concentrations of the reducing agent, the effect of particle size on the dissolution rate of MnO2 was shown to be insignificant.