IIa型HPHT合成金刚石中杂质和夹杂物的光谱特征及鉴别应用

Ying Ma, Zhili Qiu, Yuqing Zhuang, Shuqi Lai, Taijin Lu, Xiaoqin Deng
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引用次数: 0

摘要

近年来,中国已成为Ⅱa型无色HPHT合成钻石的最大生产国。而鉴定Ⅱa型HPHT合成金刚石已成为一项具有挑战性的任务。本研究试图找到鉴定Ⅱa型HPHT合成钻石的证据。收集了国内(HH, J, Z)高压高温(HPHT)生产企业的金刚石样品,研究了近3年生产的11种典型Ⅱa型金刚石样品的夹杂物和杂质分布。主要有两点认识:(1)当在DiamondviewTM等设备下对Ⅱa型金刚石的荧光颜色和图像不能给出明确的识别证据时,其圆锥形、黑丝状或细管状包裹体、细点包裹体、无形纯白铁矿、赤铁矿和磁铁矿包裹体的分布可以作为鉴定新型HPHT合成金刚石的参考依据。(2)部分样品存在可检测的杂质缺陷,其与Ni和B相关的发射峰和分布可作为HPHT合成金刚石测定的辅助特征。
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Spectroscopic Feature and Identification Application of the Impurity and Inclusion in Type IIa HPHT Synthetic Diamond
In recent years, China has become the largest producer of type Ⅱa colourless HPHT synthetic diamonds. And the identification of type Ⅱa HPHT synthetic diamond has become a challenging task. This research attempted to find the evidence of identification for type Ⅱa HPHT synthetic diamonds. Diamond samples from the high pressure and high temperature (HPHT) manufacturers in China (HH, J, Z) were collected, from which the inclusions and the distribution of impurities of 11 typical type Ⅱa diamond samples produced in the past three years were studied. Two main points of understanding were obtained: (1) When the fluorescent colour and image of type Ⅱa diamond under DiamondviewTM and other equipments can not give clear identification evidence, the conical, black thread-like or thin tubular inclusions, the distribution of fine point inclusions, shapeless cohenite, hematite, and magnetite inclusions can be used as the reference for determining the new HPHT synthetic diamonds. (2) Some samples have impurity defects which can be tested, and their emission peaks and distributions which are related to Ni and B can be used as the contributory characteristics for determining HPHT synthetic diamonds.
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