水面除油过程中有机物性质的研究

I. Bacherikova, S. Grinenko, L. Kuznetsova, V. Zazhigalov, O.V. Bacherikov
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引用次数: 1

摘要

研究了几种有机物在水域除油过程中的性能。实验结果表明,技术棉和吸水棉等可用材料可作为有效的吸附剂用于水中除油。这些吸附剂的样品机械拧干允许返回部分被吸附的油,以供下次使用。建立了吸附性质(吸附的石油质量、比油吸附量、回油量和除油选择性)和除油量与吸附-释放循环次数的关系。结果表明,在机械绞拧过程中,吸附油的数量减少,回油的质量增加。通过在汽油中冲洗使这些吸附剂再生,可以获得从水中除油的初始性能。用这些材料制备了以亚麻为原料的袋状吸附元素。确定了各吸附元件的除油量与水体清油时间的关系,确定了除油的最佳参数。结果表明,在这些材料的基础上,吸附元件的吸附量为14 ~ 16 g石油/g吸附剂,除油选择性大于70%,原油采收率大于80%,并有可能在溢油响应中重复使用。从水域中获得的除油的积极结果允许在石油泄漏的极端情况下提出可用的工业产品,如运动衫,毯子,夹克等,成功地用于石油泄漏响应。这些元素的疏水性可以改善它们在水中除油的性能。通过对吸附元素的改性,提高了吸附油的质量和比除油率,同时增加了下次使用的回油量和除油选择性。结果表明,合成的吸附元素性能不低于已知工业吸附剂。
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Investigation of organic materials nature on petrol removal from water surfacee
The properties of some organic materials in the removal of oil from water area were studied. It was shown that available materials as technical wool and sintepon can be used as effective sorbents for petroleum removal from water area. The sample mechanical wringing of these sorbents permits to return the part of adsorbed oil for its next use. The dependence of sorption properties (the adsorbed petroleum mass, specific oil adsorption, return of the oil and selectivity of petroleum removal) and petroleum removal from the number of absorption-release cycles was established. It was established that quantity of adsorbed oil decreases in other next step of removal but mass of oil returned increases in the process of mechanical wringing. The regeneration of these adsorbents by flushing in gasoline permits to obtained the initial properties in oil removal from water area. The sorption elements in the form of bags from linen with these materials were prepared. The dependence of the amount of oil removed by these sorption elements from the time of oil clearing of the water area process was determined and the optimal parameters of petroleum removal were established. It was shown that sorption elements on the base of these materials have adsorption capacity equal to 14-16 g of petroleum/g sorbent at selectivity of petroleum removal more than 70 % and oil recovery degree more than 80 % and the possibility their reusable use on oil spill response. The obtained positive results of oil removal from water area permit to propose in extreme cases of oil spills the available industrial products as jerseys, blankest, jackets etc. use successfully for petroleum spill response. The hydrophobization of these elements permits to improve their properties in oil removal from water area. As results of sorption elements modification the increase of adsorbed oil mass and specific petroleum removal at simultaneous increase of returned oil quantity for its next use and oil removal selectivity were established. It was established that synthesized sorption elements not inferior in properties known industrial sorbents for oil removal from water area.
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