碳量子点的制备与表征

Ali Muhson, S. Abbas
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摘要

文章历史:收稿日期:2019年5月22日接收日期:2019年10月03日在线日期:2019年12月25日采用简单经济的一锅法制备了碳量子点(CQDs)。以抗坏血酸为碳源,醋酸铜为催化剂加速反应。采用紫外-可见分光光度计和光致发光(PL)测量、透射电子显微镜(TEM)、x射线衍射(XRD)和傅里叶变换红外光谱(FTIR)研究了CQDs的结构和光学性质。研究了激发波长和ph对PL性质的影响。结果表明,CQDs在紫外区有较强的吸收峰。PL与激发波长有关。CQDs的发光峰随溶液pH值的降低而减小,发光峰向较短波长偏移。从TEM测量结果来看,CQDs的平均尺寸为4nm。DOI: http://dx.doi.org/10.31257/2018/JKP/2019/110207 K e y w o r d s:碳量子点的光学性质发射光谱تينوبركلاتيوكلاطاقنلاثازيوهوريضحتسابعرابجديعسنسحهتيطعيلعةرصبلاتعهاج,مولعلاتيلك,ءايزيفلانسق:تيحاخفًناثاًهكناناــــخـــصلاـــت
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Preparation and Characterization of the Carbon Quantum Dots
Article history: Received: 22 MAY, 2019 Accepted: 03 OCT, 2019 Available Online: 25 DEC, 2019 The carbon quantum dots (CQDs) were prepared by using an easy and economic one – pot method. The starting materials are the ascorbic acid as a carbon source and copper acetate as a catalyst to accelerate the reaction. The structural and optical properties of the CQDs are studied by UV-VIS spectrophotometer and photoluminescence (PL) measurements, transmission electron microscope (TEM), X-ray diffraction (XRD) and Fourier transform-infrared spectroscopy (FTIR). The excitation wavelength and the pH-dependent of PL properties was investigated also. The results show that the CQDs have strong absorption peak in the UV-region. The PL is the excitation wavelength dependent. The PL of CQDs decreases upon lowering the pH value of the solutions and the PL peaks shifted to the shorter wavelength. The average size of the CQDs is 4 nm from the TEM measurements. DOI: http://dx.doi.org/10.31257/2018/JKP/2019/110207 K e y w o r d s : Carbon quantum dot optical properties emission spectra تينوبركلا تيوكلا طاقنلا ثازيوهو ريضحت سابع رابج ديعس نسحه تيطع يلع ةرصبلا تعهاج ,مولعلا تيلك , ءايزيفلا نسق :تيحاخفًنا ثاًهكنا نا ــــ خ ـــ صلا ـــ ت
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