g-C3N4/rGO基金属氧化物半导体的合成及其光催化应用

T. Tran, Tuyen Vo, Tram Le Thi Pham, Hung Minh Ngo, M. Nguyen, H. Le, H. Nguyen
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摘要

以g-C3N4和氧化石墨烯为载体的金属氧化物半导体材料作为光催化剂,由于其在不同领域,特别是在环境处理方面的潜在应用而受到广泛的关注。本文报道了以ZnO/g-C3N4和rGO为原料,通过水热法制备ZnO/g-C3N4/rGO synthesís。考察了ZnO - c3n4的掺量对合成的纳米颗粒结构和形貌的影响。XRD、SEM、FT-IR、EDX等表征方法表明,该材料具有较高的结晶度,ZnO颗粒高度分散在g-C3N4片和还原氧化石墨烯层上。通过测定ZnO/g-C3N4/rGO在水溶液中降解环丙沙星(CIP)的光催化活性。在阳光照射240分钟后,CIP分解效率可达90%。
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Synthesis and photocatalytic application of g-C3N4/rGO based metal oxide semiconductors
Metal oxide semiconductor materials onto g-C3N4 and rGO as photocatalysts have attracted considerably due to its potential application in different fields, special in environmental treatment. In this paper, we report the synthesís of ZnO/g-C3N4/rGO through hydrothermal method from ZnO/g-C3N4 and rGO. The effect of ratio of the ZnO và g-C3N4 on the structural and morphology of the synthesized nanoparticles were perfomed. The obtained results from characterization methods such as XRD, SEM, FT-IR, EDX,… showed that the materials have a high crystallinity, and ZnO particles were dispersed highly onto g-C3N4 sheets as well as layers of graphene oxide reduced. The photocatalytic activity of ZnO/g-C3N4/rGO was estimated through the degradation of Ciprofloxacin (CIP) in aqueous solution. CIP decomposition efficiency is up to 90% after 240 minutes exposuring to sun light irradiation.
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