宽动态范围氢传感使用银金红石肖特基二极管

F. Hossein-Babaei, M. Purahmad
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引用次数: 10

摘要

研究了银金红石肖特基二极管中反向电流的氢灵敏度。将银颗粒部分烧结在热氧化钛箔上制备样品器件。在洁净空气中,该器件在200 ~ 400℃工作温度范围内表现出肖特基型的电流-电压特性。氢探测的高灵敏度和宽动态范围是通过一个模型来描述的,该模型基于在结处建立的势垒高度相对于周围大气中还原性污染物的浓度的变化,这降低了银聚集体有效表面的吸附氧覆盖率。该设备的宽动态范围允许单个传感器在50 ppm至25%的范围内测量空气中的H2污染。
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Wide dynamic range hydrogen sensing using silver-rutile Schottky diode
The hydrogen sensitivity of the reverse current in silver-rutile Schottky diode is investigated. Sample devices were prepared by the partial sintering of silver particles on thermally oxidized titanium foil. The device exhibited Schottky-type current-voltage characteristics in the 200 to 400degC operating temperature range in clean air. The high sensitivity and wide dynamic range observed for hydrogen detection are described by a model based on the variation of the height of the potential barrier established at the junction with respect to the concentration of the reducing contaminations in the surrounding atmosphere, which reduced the adsorbed oxygen coverage at the effective surface of the silver aggregate. The wide dynamic range of the device allowed a single sensor to measure H2 contamination in air in 50 ppm to 25% range.
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