O. V. Askerov, A. F. Mamedova, D. Nurullayeva, G.Dzh. Khanbabayeva
{"title":"不饱和芳香族氧化硅烷的合成与性能研究","authors":"O. V. Askerov, A. F. Mamedova, D. Nurullayeva, G.Dzh. Khanbabayeva","doi":"10.32737/2221-8688-2022-2-133-137","DOIUrl":null,"url":null,"abstract":"The method of the synthesis of unsaturated aromatic oxiranosilanes by interaction of trialkyl- (aryl)-hydridesilanes with aromatic oxiranes of the acetylene series in the presence of catalyst (platinumhydrochloric acid) in a medium of absolute benzene (yield up to 82-85%) was developed and their properties studied. It was showed that the addition reaction proceeded on a triple bond according to Farmer's rule with the formation of trans-adducts and the maintenance of the oxirane ring. The composition and structure of the obtained unsaturated aromatic oxiranosilanes were confirmed by IR and PMR spectra. It revealed that the obtained unsaturated aromatic oxiranosilanes were highly reactive compounds and can undergo the reaction with nucleophilic and electrophilic reagents","PeriodicalId":10015,"journal":{"name":"Chemical Problems","volume":"40 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"SYNTHESIS AND PROPERTIES OF UNSATURATED AROMATIC OXIRANOSILANES\",\"authors\":\"O. V. Askerov, A. F. Mamedova, D. Nurullayeva, G.Dzh. Khanbabayeva\",\"doi\":\"10.32737/2221-8688-2022-2-133-137\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The method of the synthesis of unsaturated aromatic oxiranosilanes by interaction of trialkyl- (aryl)-hydridesilanes with aromatic oxiranes of the acetylene series in the presence of catalyst (platinumhydrochloric acid) in a medium of absolute benzene (yield up to 82-85%) was developed and their properties studied. It was showed that the addition reaction proceeded on a triple bond according to Farmer's rule with the formation of trans-adducts and the maintenance of the oxirane ring. The composition and structure of the obtained unsaturated aromatic oxiranosilanes were confirmed by IR and PMR spectra. It revealed that the obtained unsaturated aromatic oxiranosilanes were highly reactive compounds and can undergo the reaction with nucleophilic and electrophilic reagents\",\"PeriodicalId\":10015,\"journal\":{\"name\":\"Chemical Problems\",\"volume\":\"40 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Problems\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.32737/2221-8688-2022-2-133-137\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Problems","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.32737/2221-8688-2022-2-133-137","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
SYNTHESIS AND PROPERTIES OF UNSATURATED AROMATIC OXIRANOSILANES
The method of the synthesis of unsaturated aromatic oxiranosilanes by interaction of trialkyl- (aryl)-hydridesilanes with aromatic oxiranes of the acetylene series in the presence of catalyst (platinumhydrochloric acid) in a medium of absolute benzene (yield up to 82-85%) was developed and their properties studied. It was showed that the addition reaction proceeded on a triple bond according to Farmer's rule with the formation of trans-adducts and the maintenance of the oxirane ring. The composition and structure of the obtained unsaturated aromatic oxiranosilanes were confirmed by IR and PMR spectra. It revealed that the obtained unsaturated aromatic oxiranosilanes were highly reactive compounds and can undergo the reaction with nucleophilic and electrophilic reagents
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
