{"title":"1-芳基-2,5-二硫腙二碳酰胺三苯基锡和二丁基锡配合物的合成及表征","authors":"R. Rastogi, K. Singh, V. Jaiswal","doi":"10.1155/2014/529764","DOIUrl":null,"url":null,"abstract":"Organotin complexes of the types Ph3SnL and Bu2SnL [where Ph = phenyl and Bu = butyl; HL = 1-phenyl-2,5-dithiohydrazodicarbonamide (HPhthc), 1-benzyl-2,5-dithiohydrazodicarbonamide (Hbzthc), 1-(4-ethoxyphenyl)-2,5-dithiohydrazodicarbonamide (HEtOPhthc)] have been prepared. Molar conductance studies demonstrate the nonionic behavior of the complexes. The 1H and 13C nuclear magnetic resonance and FAB mass spectra of the complexes are consistent with the proposed stoichiometry. Infrared spectra suggest an anionic bidentate coordinating behavior of the ligands.","PeriodicalId":15303,"journal":{"name":"Journal of Chemical Technology & Biotechnology","volume":"227 1","pages":"1-5"},"PeriodicalIF":0.0000,"publicationDate":"2014-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Synthesis of Triphenyltin (IV) and Dibutyltin (IV) Complexes of 1-Aryl-2,5-dithiohydrazodicarbonamides and Their Characterization\",\"authors\":\"R. Rastogi, K. Singh, V. Jaiswal\",\"doi\":\"10.1155/2014/529764\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Organotin complexes of the types Ph3SnL and Bu2SnL [where Ph = phenyl and Bu = butyl; HL = 1-phenyl-2,5-dithiohydrazodicarbonamide (HPhthc), 1-benzyl-2,5-dithiohydrazodicarbonamide (Hbzthc), 1-(4-ethoxyphenyl)-2,5-dithiohydrazodicarbonamide (HEtOPhthc)] have been prepared. Molar conductance studies demonstrate the nonionic behavior of the complexes. The 1H and 13C nuclear magnetic resonance and FAB mass spectra of the complexes are consistent with the proposed stoichiometry. Infrared spectra suggest an anionic bidentate coordinating behavior of the ligands.\",\"PeriodicalId\":15303,\"journal\":{\"name\":\"Journal of Chemical Technology & Biotechnology\",\"volume\":\"227 1\",\"pages\":\"1-5\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2014-03-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Chemical Technology & Biotechnology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1155/2014/529764\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Chemical Technology & Biotechnology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1155/2014/529764","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis of Triphenyltin (IV) and Dibutyltin (IV) Complexes of 1-Aryl-2,5-dithiohydrazodicarbonamides and Their Characterization
Organotin complexes of the types Ph3SnL and Bu2SnL [where Ph = phenyl and Bu = butyl; HL = 1-phenyl-2,5-dithiohydrazodicarbonamide (HPhthc), 1-benzyl-2,5-dithiohydrazodicarbonamide (Hbzthc), 1-(4-ethoxyphenyl)-2,5-dithiohydrazodicarbonamide (HEtOPhthc)] have been prepared. Molar conductance studies demonstrate the nonionic behavior of the complexes. The 1H and 13C nuclear magnetic resonance and FAB mass spectra of the complexes are consistent with the proposed stoichiometry. Infrared spectra suggest an anionic bidentate coordinating behavior of the ligands.
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